In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Incorporation of fluoroalkyl motifs in pharmaceuticals can enhance the therapeutic profiles of
the parent molecules. The hydrofluoroalkylation of alkenes has emerged as a promising …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …

Vicinal diamines are privileged synthetic motifs in chemistry due to their prevalence and
powerful applications in bioactive molecules, pharmaceuticals, and ligand design for …

The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

Abundant aromatic carboxylic acids exist in great structural diversity from nature and
synthesis. To date, the synthetically valuable decarboxylative functionalization of benzoic …

Reforming sustainable 3d-metal-based visible light catalytic platforms for inert bulk chemical
activation is highly desirable. Herein, we demonstrate the use of a Brønsted acid to unlock …