From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Blatter radicals as bipolar materials for symmetrical redox-flow batteries

JS Steen, JL Nuismer, V Eiva… - Journal of the …, 2022 - ACS Publications
Redox-active organic molecules are promising charge-storage materials for redox-flow
batteries (RFBs), but material crossover between the posolyte and negolyte and chemical …

High-spin organic molecules

NM Gallagher, A Olankitwanit… - The Journal of Organic …, 2015 - ACS Publications
Organic molecules with high-spin ground states, besides being fundamentally interesting,
possess numerous potential applications in diverse fields such organic magnetism, MRI …

Magnetic Bistability in an Organic Radical-Based Charge Transfer Cocrystal

W Lai, Y Bu, W Xiao, H Liu, J Guo, L Zhao… - Journal of the …, 2023 - ACS Publications
We report herein an organic charge transfer cocrystal complex, consisting of a stable radical
TPVr and an electron acceptor TCNQF 4, as a rare sort of all-organic-based magnetic …

Recent advances of stable Blatter radicals: synthesis, properties and applications

Y Ji, L Long, Y Zheng - Materials Chemistry Frontiers, 2020 - pubs.rsc.org
Radicals, organic molecules with unpaired electrons, are applied across different scientific
disciplines such as electronics, energy storage and biochemistry. Among them, due to the …

Thermally and magnetically robust triplet ground state diradical

N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …

Recent advances in organic radicals and their magnetism

S Kumar, Y Kumar, SK Keshri, P Mukhopadhyay - Magnetochemistry, 2016 - mdpi.com
The review presents an overview of the organic radicals that have been designed and
synthesized recently, and their magnetic properties are discussed. The π-conjugated …

Insights into the magnetism and phase transitions of organic radical-based materials

M Deumal, S Vela, M Fumanal, J Ribas-Arino… - Journal of Materials …, 2021 - pubs.rsc.org
Organic radicals have been consistently regarded as promising building blocks for the next
generation of applied materials. Multiple radical families have been developed and …

Room-Temperature Magnetic Bistability in a Salt of Organic Radical Ions

AI Taponen, A Ayadi, MK Lahtinen… - Journal of the …, 2021 - ACS Publications
Cocrystallization of 7, 7′, 8, 8′-tetracyanoquinodimethane radical anion (TCNQ–•) and 3-
methylpyridinium-1, 2, 3, 5-dithiadiazolyl radical cation (3-MepyDTDA+•) afforded …