Bioinspired applications of porphyrin derivatives

JM Park, KI Hong, H Lee, WD Jang - Accounts of chemical …, 2021 - ACS Publications
Conspectus Porphyrin derivatives are ubiquitous in nature and have important biological
roles, such as in light harvesting, oxygen transport, and catalysis. Owing to their intrinsic π …

Design and applications of molecular probes containing porphyrin derivatives

H Lee, KI Hong, WD Jang - Coordination Chemistry Reviews, 2018 - Elsevier
Porphyrins are heterocyclic macrocycle organic compounds, composed of four modified
pyrrole subunits interconnected at their α carbon atoms via methine bridges. Because of …

Porphyrin Atropisomerism as a Molecular Engineering Tool in Medicinal Chemistry, Molecular Recognition, Supramolecular Assembly, and Catalysis

S Maguire, G Strachan, K Norvaiša… - … A European Journal, 2024 - Wiley Online Library
Porphyrin atropisomerism, which arises from restricted σ‐bond rotation between the
macrocycle and a sufficiently bulky substituent, was identified in 1969 by Gottwald and …

Halogen‐Bonding Strapped Porphyrin BODIPY Rotaxanes for Dual Optical and Electrochemical Anion Sensing

Y Cheong Tse, R Hein, EJ Mitchell… - … A European Journal, 2021 - Wiley Online Library
Anion receptors employing two distinct sensory mechanisms are rare. Herein, we report the
first examples of halogen‐bonding porphyrin BODIPY [2] rotaxanes capable of both …

Porphyrin-based nanoporous materials for photocatalytic applications

JH Lee, Y Kim, S Oh, WD Jang - Applied Physics Reviews, 2024 - pubs.aip.org
Alongside the unique photophysical properties, porphyrin derivatives play key roles in light
harvesting of photosynthetic organisms. Due to their symmetrical structure, porphyrin …

Access to 2-Alkyl/Aryl-4-(1H)-Quinolones via Orthogonal “NH3” Insertion into o-Haloaryl Ynones: Total Synthesis of Bioactive Pseudanes, Graveoline, Graveolinine …

S Singh, S Nerella, S Pabbaraja, G Mehta - Organic letters, 2020 - ACS Publications
An efficient one-pot synthesis of 4-(1 H)-quinolones through an orthogonal engagement of
diverse o-haloaryl ynones with ammonia in the presence of Cu (I), involving tandem Michael …

Rh-Catalyzed Ortho C–H Alkynylation of Aromatic Aldehydes

E Tan, LJ Nannini, O Stoica, AM Echavarren - Organic Letters, 2021 - ACS Publications
The Rh (III)-catalyzed ortho-alkynylation of benzaldehydes is enabled by the transient
formation of an imine as a directing group. A broad scope of substrates was obtained under …

Porphyrin chemodosimeters: synthesis, electrochemical redox properties and selective 'naked-eye'detection of cyanide ions

MK Chahal, M Sankar - RSC advances, 2015 - pubs.rsc.org
Dicyanovinyl appended β-pyrrole substituted porphyrins have been synthesized and utilized
as chemodosimeters for ratiometric and colorimetric sensing of cyanide ions. In addition to …

Glycoporphyrin catalysts for efficient C–H bond aminations by organic azides

G Tseberlidis, P Zardi, A Caselli, D Cancogni… - …, 2015 - ACS Publications
We report herein the synthesis of new glycoporphyrin ligands which bear a glucopyranoside
derivative on each meso-aryl moiety of the porphyrin skeleton. The saccharide unit is directly …

Dynamic Metalloporphyrin‐Based [2] Rotaxane Molecular Shuttles Stimulated by Neutral Lewis Base and Anion Coordination

JT Wilmore, Y Cheong Tse, A Docker… - … A European Journal, 2023 - Wiley Online Library
A series of dynamic metalloporphyrin [2] rotaxane molecular shuttles comprising of bis‐
functionalised Zn (II) porphyrin axle and pyridyl functionalised macrocycle components are …