Formation and stabilization of nanosized Pd particles in catalytic systems: Ionic nitrogen compounds as catalytic promoters and stabilizers of nanoparticles

VM Chernyshev, OV Khazipov, DB Eremin… - Coordination Chemistry …, 2021 - Elsevier
Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …

Flow chemistry of main group and transition metal complexes

T Scattolin, A Simoens, CV Stevens, SP Nolan - Trends in Chemistry, 2022 - cell.com
Continuous flow reactors have earned their place as an important technology in organic
synthesis, receiving increased interest in the past decade. The favorable heat and mass …

Boron‐Mediated Regioselective Aromatic C−H Functionalization via an Aryl BF2 Complex

GH Shinde, H Sundén - Chemistry–A European Journal, 2023 - Wiley Online Library
An efficient regioselective functionalization of 2‐aryl‐heteroarenes and aryl aldehydes via
an azaaryl BF2 complex has been developed. Mechanistically the reaction comprises …

Hypercrosslinked Polymer Platform-Anchored Single-Site Heterogeneous Pd–NHC Catalysts for Diverse C–H Functionalization

T Mandal, M Mondal, J Choudhury - Organometallics, 2021 - ACS Publications
We demonstrate a new class of hypercrosslinked polymer (HCP) platform-anchored single-
site heterogenized Pd–NHC catalysts for multipurpose C–H functionalization reactions. This …

Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation

D Meng, J Bi, Y Dong, B Hao, K Qin, T Li… - Chemical …, 2020 - pubs.rsc.org
In this work, we report the first use of a salen-based hypercrosslinked polymer-supported Pd
catalyst to carry out C–H halogenation. This catalyst can effectively catalyze C–H …

Catalytic Advancements: Optimizing Pd-Based Cross-Coupling Reactions Through Flow Chemistry

IS Patel, G Ganesan, S Jain - Organic Process Research & …, 2024 - ACS Publications
Flow chemistry is a method of conducting a reaction in continuous flow through channels by
pumping the reactants into the system. This advanced method offers rapid and efficient …

One Dianionic Luminophore with Three Coordination Modes Binding Four Different Metals: Toward Unexpectedly Phosphorescent Transition Metal Complexes

TM Kirse, I Maisuls, L Spierling, A Hepp… - Advanced …, 2024 - Wiley Online Library
This work reports on a battery of coordination compounds featuring a versatile dianionic
luminophore adopting three different coordination modes (mono, bi, and tridentate) while …

Steric effect of NHC ligands in Pd (II)–NHC-catalyzed non-directed C–H acetoxylation of simple arenes

T Mandal, S Yadav, J Choudhury - Journal of Organometallic Chemistry, 2021 - Elsevier
Although there has been a lot of progress in oxidative arene C–H functionalization reactions
catalyzed by Pd (II/IV) system, the non-directed, site-selective functionalization of arene …

Acceptorless dehydrogenation of 4-methylpiperidine by supported pincer-ligated iridium catalysts in continuous flow

K Chakrabarti, A Spangenberg… - Catalysis Science & …, 2023 - pubs.rsc.org
Finding alternative and sustainable ways to produce, store and convert energy is key for
reducing fossil fuel-based CO2 emissions. In this transformation, hydrogen for energy …

Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C–H functionalization

T Mandal, TK Dutta, S Mohanty… - Chemical …, 2021 - pubs.rsc.org
Three-dimensionally propagated imidazolium-containing mesoporous coordination polymer
and organic polymer-based platforms were successfully exploited to develop single-site …