Passive films on stainless steels—chemistry, structure and growth

COA Olsson, D Landolt - Electrochimica acta, 2003 - Elsevier
The outstanding corrosion resistance of stainless steels results from the presence of a thin
oxide—'passive'—film on the metal surface, typically 1–3 nm thick. The characterisation of …

Indentation induced dislocation nucleation: The initial yield point

WW Gerberich, JC Nelson, ET Lilleodden, P Anderson… - Acta Materialia, 1996 - Elsevier
Yield points have been detected in both GaAs and Fe 3wt% Si single crystals when
contacting the surface with sharp diamond tips. The present study concentrates mostly on …

The structure of the passive film that forms on iron in aqueous environments

AJ Davenport, LJ Oblonsky, MP Ryan… - Journal of the …, 2000 - iopscience.iop.org
Metals are protected from corrosion in many aqueous environments by the formation of
“passive” oxide films that are typically only a few nanometers thick. The technological …

Coupling between ionic defect structure and electronic conduction in passive films on iron, chromium and iron–chromium alloys

M Bojinov, G Fabricius, T Laitinen, K Mäkelä, T Saario… - Electrochimica …, 2000 - Elsevier
A quantitative kinetic model is presented for the steady-state passive films on Fe, Cr and Fe–
Cr alloys. It emphasises the coupling between the ionic defect structure and electronic …

The passivity of iron in the presence of ethylenediaminetetraacetic acid I. General electrochemical behavior

E Sikora, DD Macdonald - Journal of the Electrochemical Society, 2000 - iopscience.iop.org
During the past eight decades, the passive film formed on iron in neutral and alkaline
aqueous solutions has been the subject of numerous investigations1-5 aimed at developing …

The role of oxides in reduction reactions at the metal-water interface

MM Scherer, BA Balko, PG Tratnyek - 1998 - ACS Publications
The oxide layer that lies at the iron-water interface under environmental conditions can
influence the reduction of solutes by acting as a passive film, semiconductor, or coordinating …

Effect of temperature on corrosion of carbon steel in simulated concrete pore solution under anoxic conditions

J Qiu, Y Li, Y Xu, A Wu, DD Macdonald - Corrosion Science, 2020 - Elsevier
The effect of temperature on the passive state of carbon steel in simulated concrete pore
solution is examined. The mixed potential model (MPM) was used to optimize the …

Oxide formation and conversion on carbon steel in mildly basic solutions

W Xu, K Daub, X Zhang, JJ Noel, DW Shoesmith… - Electrochimica …, 2009 - Elsevier
Surface oxide film growth and conversion processes on carbon steel were studied using a
range of electrochemical techniques and ex situ surface analyses. The electrochemical …

The structure and electronic properties of passive and prepassive films of iron in borate buffer

SP Harrington, F Wang, TM Devine - Electrochimica acta, 2010 - Elsevier
The films that form on pure iron during potentiodynamic anodic polarization in aqueous
borate buffer were investigated by surface enhanced Raman spectroscopy (SERS), and by …

Instrumental analysis of microbiologically influenced corrosion

G Chen, RJ Palmer, DC White - Biodegradation, 1997 - Springer
Appropriate application of techniques for detection andmonitoring of microbiologically
influenced corrosion isessential for understanding the mechanistic nature of theinteractions …