This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …

Nitrones are important compounds and are highly useful in many aspects. The first part
describes the methods for synthesis of nitrones, which are useful and environmentally …

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

Conspectus The combination of two or more unsaturated structural units to form cyclic
organic compounds is commonly referred to as cycloaddition, and the combination of two …

Abstract The regio‐and enantioselective (3+ 3) cycloaddition of nitrones with 2‐
indolylmethanols was accomplished by the cooperative catalysis of hexafluoroisopropanol …

The transformations of cyclopropenes have attracted the attention of organic chemists for
decades. As readily accessible strained carbocycles, cyclopropenes show a diverse range …

Enantioselective Silver-Catalyzed Transformations | Chemical Reviews ACS ACS Publications
C&EN CAS Find my institution Log In Chemical Reviews ACS Publications. Most Trusted. Most …

Although best known for their [3+ 2]‐dipolar cycloaddition reactivity and use in the
preparation of isoxazolines and isoxazolidines, nitrones are versatile reagents that undergo …

Herein we report a mild, transition-metal-free, highly diastereoselective Lewis acid catalyzed
methodology toward the synthesis of isoxazolidine-based diazo compounds from the …

3-Spiro [cyclopropa [a] pyrrolizine]-and 3-spiro [3-azabicyclo [3.1. 0] hexane] oxindoles were
prepared in moderate to high yields via one-pot three-component reactions using …