Hierarchically structured zeolites: from design to application

LH Chen, MH Sun, Z Wang, W Yang, Z Xie… - Chemical …, 2020 - ACS Publications
Hierarchical zeolites combine the intrinsic catalytic properties of microporous zeolites and
the enhanced access and transport of the additional meso-and/or macroporous system …

Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol

SS Tabibian, M Sharifzadeh - Renewable and Sustainable Energy …, 2023 - Elsevier
Methanol could be considered one of four important basic chemicals, and is produced at the
rate of more than 98 million tons yearly. About 30% of methanol is utilized in fuel …

Roadmap to the sustainable synthesis of polymers: From the perspective of CO2 upcycling

K Sadeghi, Y Jeon, J Seo - Progress in Materials Science, 2023 - Elsevier
The demand for virgin polymers is constantly increasing owing to the desired performance
and low recycling rates of polymers; however, this exacerbates significant plastic-industry …

Influence of zeolite ZSM-5 synthesis protocols and physicochemical properties in the methanol-to-olefin process

HS Kamaluddin, X Gong, P Ma, K Narasimharao… - Materials Today …, 2022 - Elsevier
To address the growing concerns regarding climate change and the depletion of fossil
resources, the zeolite ZSM-5 catalyzed methanol-to-olefin (MTO) process is considered to …

Strategies to control reversible and irreversible deactivation of ZSM-5 zeolite during the conversion of methanol to propylene (MTP): A review

A Zabihpour, J Ahmadpour, F Yaripour - Chemical Engineering Science, 2023 - Elsevier
Despite the favorable properties, ZSM-5 still suffers from deposition of coke in vital pores of
catalyst (reversible deactivation) as well as dealumination (irreversible deactivation) due to …

Sustainable synthesis of drop-in chemicals from biomass via chemical catalysis: Scopes, challenges, and the way forward

S Dutta - Energy & Fuels, 2023 - ACS Publications
A handful of small organics, namely, ethylene, propylene, butadiene, benzene, toluene,
xylenes, and methanol, produced from petroleum and other fossilized carbon-based …

Conversion of dimethyl ether to lower olefines

AQ Bukhorov, SC Aslanov, NI Fayzullaev - AIP Conference …, 2022 - pubs.aip.org
The study considered catalytically active systems in the synthesis of olefins below DME
based on Zn-Zr-Cu* HSZ* Al2O3. The hydrogen form of zeolite (H+) was obtained by …

Suppression of the aromatic cycle in methanol‐to‐olefins reaction over ZSM‐5 by post‐synthetic modification using calcium

I Yarulina, S Bailleul, A Pustovarenko… - …, 2016 - Wiley Online Library
Incorporation of Ca in ZSM‐5 results in a twofold increase of propylene selectivity (53%), a
total light‐olefin selectivity of 90%, and a nine times longer catalyst lifetime (throughput 792 …

What is the true cost of producing propylene from methanol? The role of externalities

DF Rodríguez-Vallejo, G Guillén-Gosálbez… - ACS Sustainable …, 2020 - ACS Publications
The demand for olefins has increased steadily in recent years, with a propylene demand
around 100 million tons per year and an expected annual growth of 3–4%. Most propylene …

Phosphorus-modified b-axis oriented hierarchical ZSM-5 zeolites for enhancing catalytic performance in a methanol to propylene reaction

R Feng, X Yan, X Hu, Y Zhang, J Wu, Z Yan - Applied Catalysis A: General, 2020 - Elsevier
In this work, a b-axis oriented hierarchical ZSM-5 zeolite was prepared with glucose as an
additive and further modified by phosphorus to improve the propylene selectivity and …