Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

As a rapidly growing field across all areas of chemistry, CH activation/functionalisation is
being used to access a wide range of important molecular targets. Of particular interest is the …

In contrast to the traditional and widely-used cycloaddition reactions involving at least a π
bond component, a [2σ+ 2σ] radical cycloaddition between bicyclo [1.1. 0] butanes (BCBs) …

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Despite the large number of disparate approaches for the direct selective partial oxidation of
methane, none of them has translated into an industrial process. The oxidation of methane …

The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …

Polyolefins comprise a major fraction of single-use plastics, yet their catalytic deconstruction/
recycling has proven challenging due to their inert saturated hydrocarbon connectivities …

Hydride complexes of copper, silver, and gold encompass a broad array of structures, and
their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis …

An isolated Csingle bondH bond in a molecule has a very low reactivity owing to the large
kinetic barrier associated to the Csingle bondH bond cleavage and the apolar nature of this …