Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …

The preparation of novel stable radical systems that survive and may be manipulated under
harsh conditions is essential for their practical applications, such as energy storage and …

Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …

The Gouterman four-orbital model conceptualizes porphyrin UV–visible spectra as
dominated by four frontier molecular orbitals─ two nearly degenerate HOMOs and two …

The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …

A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …

Novel cobalt and zinc complexes with the tetradentate ppq (8-(1 ″, 10 ″-phenanthrol-2 ″-
yl)-2-(pyrid-2′-yl) quinoline) ligand have been synthesized and fully characterized …

Four new β-functionalized π-extended cobalt corroles with one and two dicyanovinyl (DCV)
or dicyanobutadienyl (DCBD) moieties at the 3-and 3, 17-positions have been synthesized …

A lot of effort is nowadays put into the development of novel water oxidation catalysts. In this
context, mechanistic studies are crucial in order to elucidate the reaction mechanisms …