Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Boron containing compounds as protease inhibitors

R Smoum, A Rubinstein, VM Dembitsky… - Chemical …, 2012 - ACS Publications
Proteases form one of the largest and more important groups of enzymes. They selectively
catalyze the hydrolysis of peptide bonds and can be divided into four major classes …

Boryllithium: isolation, characterization, and reactivity as a boryl anion

Y Segawa, M Yamashita, K Nozaki - Science, 2006 - science.org
Nucleophilic, anionic boryl compounds are long-sought but elusive species. We report that
reductive cleavage of the boron-bromine bond in N, N′-bis (2, 6-diisopropylphenyl)-2 …

A novel shear-stiffening supramolecular material derived from diboron structure

Q Wu, Y Peng, H Xiong, Y Hou, M Cai, Y Wang… - Science China …, 2023 - Springer
Abstract Shear-stiffening polyborosiloxane (PBS), well-known as “silly putty”,“bouncing
putty” or “solid-liquid”, has been widely used in protective armors, sport equipment, toys and …

Natural and synthetic small boron-containing molecules as potential inhibitors of bacterial and fungal quorum sensing

VM Dembitsky, AAA Al Quntar, M Srebnik - Chemical Reviews, 2011 - ACS Publications
Chemical communication is a phenomenon exhibited by many different organisms and
nowadays is one of the most prominent research areas at the chemistry-microbiology …

Silylboranes as new tools in organic synthesis

T Ohmura, M Suginome - Bulletin of the Chemical Society of …, 2009 - academic.oup.com
New reactivities of silylboranes are described with their applications to organic synthesis.
The silylboranes add to unsaturated organic compounds such as alkynes, alkenes, 1, 3 …

DFT studies on the mechanism of the diboration of aldehydes catalyzed by copper (I) boryl complexes

H Zhao, L Dang, TB Marder, Z Lin - Journal of the American …, 2008 - ACS Publications
The detailed mechanism for the diboration of aldehydes catalyzed by (NHC) Cu (boryl)
complexes (NHC= N-heterocyclic carbene) was studied with the aid of DFT by calculating …

Enriched 10B-diboron reagents synthesis from 10BF3

D Chen, L Xu, Z Wang, C Liu - Chem, 2023 - cell.com
Stable isotopes have become vital tools in drug development and discovery. Because of the
unique high neutron absorption properties of boron-10, boron neutron capture therapy …

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

C Kojima, KH Lee, Z Lin… - Journal of the American …, 2016 - ACS Publications
In the absence of transition metal catalysts, the unsymmetrical diborane (4), pinB-BMes2,
reacted with alkynes to afford diborylalkenes. The isomer ratio of the products could be …

NHC‐Stabilized Dialanes(4) of Al2Mes4

L Werner, J Hagn, U Radius - Chemistry–A European Journal, 2023 - Wiley Online Library
The synthesis and characterization of novel N‐heterocyclic carbene (NHC) stabilized
dialanes Al2Mes4 as well as first investigations concerning the reactivity of these …