Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects

F Afshariazar, A Morsali - Chemical Society Reviews, 2025 - pubs.rsc.org
Owing to increasing global demand for the development of multifunctional advanced
materials with various practical applications, great attention has been paid to metal–organic …

New Pillar-MOF with Nitrogen-Donor Sites for CO2 Adsorption

A Lancheros, S Goswami, X Zarate… - Crystal Growth & …, 2024 - ACS Publications
A new pillar-MOF [Zn2 (L)(DABCO)] was solvothermally synthesized by using a new linker
(L= 4, 4′-(1, 4-phenylenebis (3, 5-dimethyl-1 H-pyrazole-4, 1-diyl)) dibenzoic acid), Zn …

Enhanced water stability of MOFs via multiple hydrogen bonds and their application in water harvesting

YC Wang, MH Chen, ZW Fan, Y Wang… - Chemical …, 2024 - pubs.rsc.org
A mechanism based on multiple hydrogen bonds was proposed to describe the great water
stability of some hydrated Cu paddle-wheel-based MOFs, which was demonstrated through …

Oxone-DMSO Triggered Methylene Insertion and C(sp2)−C(sp3)-H−C(sp2) Bond Formation to Access Functional Bis-Heterocycles

J Kour, V Venkateswarlu, PK Verma… - The Journal of …, 2020 - ACS Publications
Metal-free insertion of a methylene group was achieved for the construction of a new C (sp2)–
C (sp3)-H–C (sp2) bond in order to prepare novel bis-heterocyclic scaffolds. The complete …

An electroactive zinc-based metal–organic Framework: bifunctional fluorescent quenching behavior and direct observation of nitrobenzene

CM Ngue, MK Leung, KL Lu - Inorganic Chemistry, 2020 - ACS Publications
This work reports on the facile synthesis, characterization, and electroactivity of a zinc-based
[Zn3 (TTPA) 2 (DHTP) 3]· 2DMF (1, TTPA= tris (4-(1 H-1, 2, 4-triazol-1-yl) phenyl) amine …

A Microporous Heterovalent Copper–Organic Framework Based on [Cu2I]n and Cu2(CO2)4 Secondary Building Units: High Performance for CO2 Adsorption …

J Yuan, J Li, L Kan, L Zou, J Zhao, DS Li… - Crystal Growth & …, 2018 - ACS Publications
A microporous heterovalent Cu-based MOF,[(Cu2I) Cu2L2 (H2O) 2] 22+· 2NO3–· 5DMF
(1)(H2L= 5-(4 H-1, 2, 4-triazol-4-yl) benzene-1, 3-dicarboxylic acid, DMF= N, N …

Tuning the structures of three complexes with (4, 4) topologies based on imidazole-containing ligand via auxiliary dicarboxylates

H Liu, YT Zhang, L Luo, K Chen - Journal of Molecular Structure, 2024 - Elsevier
Solvothermal reactions of a tetradentate imidazole-containing ligand, 3, 3′, 5, 5′-tetra (1H-
imidazol-1-yl)-1, 1′-biphenyl (L), combined with Zn (II) salt in the presence of varied …

Metal–organic framework structures of fused hexagonal motifs with cuprophilic interactions of a triangular Cu (i) 3 (pyrazolate-benzoate) metallo-linker

S Menzel, T Heinen, I Boldog, THY Beglau, S Xing… - …, 2022 - pubs.rsc.org
The reaction of the N, O-heteroditopic bifunctional ligand 4-(3, 5-dimethyl-1H-pyrazol-4-yl)
benzoic acid (H2mpba) with Cu (NO3) 2· 2.5 H2O and Zn (NO3) 2· 4H2O or Zn (CH3COO) 2 …

Exchange coupled Co (II) based layered and porous metal–organic frameworks: structural diversity, gas adsorption, and magnetic properties

AK Kharwar, S Konar - Dalton Transactions, 2020 - pubs.rsc.org
Four new Co (II) based metal–organic frameworks (MOFs)({[Co3 (L)(TDCA) 3 (DMF) 2] n·
2nCH3CN})(1),({[Co3 (L) 2 (BDCA) 3] n· 2nCH3CN})(2),{[Co2 (L) 2 (CA) 2] n· 4nCH3CN}(3) …

Facile synthesis of bis-1, 3-dicarbonyl compounds using inert dichloromethane as a one-carbon source

LM Jiang, K Xiang, HJ Jiao, JL Yang, HT Qu, XT Xu… - Tetrahedron …, 2023 - Elsevier
A simple and convenient procedure for the preparation of valuable bis-1, 3-dicarbonyl-
substituted methane compounds and their derivatives has been developed using inert …