Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications

S Hameury, P de Frémont, P Braunstein - Chemical Society Reviews, 2017 - pubs.rsc.org
Ligand design has met with considerable success with both categories of hybrid ligands,
which are characterized by chemically different donor groups, and of N-heterocyclic …

Current advances on ruthenium (II) N-heterocyclic carbenes in hydrogenation reactions

DA Hey, RM Reich, W Baratta, FE Kühn - Coordination Chemistry Reviews, 2018 - Elsevier
This review provides a brief overview of advances on ruthenium (II) N-heterocyclic carbene
complexes (NHCs) applied for hydrogenation reactions undertaken during the last five …

A study on the catalytic hydrogenation of N-ethylcarbazole on the mesoporous Pd/MoO3 catalyst

S Fei, B Han, L Li, P Mei, T Zhu, M Yang… - International Journal of …, 2017 - Elsevier
Mesoporous MoO 3 shows an apparent activity in the catalytic hydrogenation of N-
ethylcarbazole (NEC), where a significant amount of tetrahydro-N-ethylcarbazole (4H-NEC) …

Recent Advances in the Syntheses and Catalytic Applications of Homonuclear Ru‐, Rh‐, and Ir‐Complexes of CNHC^C Cyclometalated Ligands

CS Tiwari, PM Illam… - Chemistry–A European …, 2021 - Wiley Online Library
In the past few decades, chemistry of cyclometalated species has gained momentum with
increased applications in several areas of scientific developments. Cyclometalation …

On the concept of hemilability: Insights into a donor-functionalized iridium (I) NHC motif and its impact on reactivity

K Riener, MJ Bitzer, A Pöthig, A Raba… - Inorganic …, 2014 - ACS Publications
Novel iridium (I) complexes bearing N-donor-functionalized N-heterocyclic carbene ligands
were synthesized. Although hemilabile coordination of the attached donor is considered …

Bis(ether-functionalized NHC) Nickel(II) Complexes, Trans to Cis Isomerization Triggered by Water Coordination, and Catalytic Ethylene Oligomerization

S Hameury, P de Fremont, PAR Breuil… - …, 2015 - ACS Publications
The new nickel (II) complexes containing NHC ligands N-substituted by a CH2CH2OR ether
group (R= Me or Ph)[NiCl2 {ImMes (C2OMe)} 2](6),[NiCl2 {Im n-Bu (C2OMe)} 2](7),[NiBr2 …

Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development

RO Pankov, DO Prima, VP Ananikov - Coordination Chemistry Reviews, 2024 - Elsevier
In the field of catalytic chemistry, metal complexes containing N-heterocyclic carbenes
(NHCs) have gained significant attention due to their versatile nature and wide range of …

Synthesis, crystal structures, characterization and biological studies of nitrile-functionalized silver (I) N-heterocyclic carbene complexes

RA Haque, SY Choo, S Budagumpi, AAA Abdullah… - Inorganica Chimica …, 2015 - Elsevier
The synthesis of a series of silver (I) complexes (3a–d),[1-(2′/3′-methylbenzyl)-3-(2 ″/3
″-benzonitrile) benzimidazol-2-ylidenesilver (I)] PF 6, of nitrile-functionalized N-heterocyclic …

Selective hydrogenation of carbonyl compounds and olefins using an efficient combination of homogeneous RuCl3/1, 10-Phenanthroline

N Sarki, S Kumawat, M Choudhary, A Narani… - Journal of …, 2024 - Elsevier
Hydrogenation of organic compounds with molecular hydrogen is an atom economic
reaction and plays a key role in chemical synthesis. Here, we report the hydrogenation of …

Sterically driven synthesis of ruthenium and ruthenium–silver N-heterocyclic carbene complexes

C Cesari, S Conti, S Zacchini, V Zanotti… - Dalton …, 2014 - pubs.rsc.org
A straightforward and efficient synthetic route to novel Ru N-heterocyclic carbene (NHC)
complexes by transmetallation of non-bulky silver NHC to ruthenium dicarbonyl …