Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Fatty acids and their derivatives as renewable platform molecules for the chemical industry

U Biermann, UT Bornscheuer… - Angewandte Chemie …, 2021 - Wiley Online Library
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the
chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 …

Crystallization of biodegradable and biobased polyesters: Polymorphism, cocrystallization, and structure-property relationship

Y Zheng, P Pan - Progress in Polymer Science, 2020 - Elsevier
In the past two decades, synthetic biodegradable and biobased polyesters have emerged as
a sustainable alternative to traditional petroleum-derived polymers for diverse range of …

Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

Update and challenges in organo-mediated polymerization reactions

WN Ottou, H Sardon, D Mecerreyes, J Vignolle… - Progress in Polymer …, 2016 - Elsevier
Organocatalysis has become a very powerful tool for precision macromolecular chemistry,
as judged by the number of articles published in this field in the past decade. A variety of …

Lewis pair polymerization: perspective on a ten-year journey

ML McGraw, EYX Chen - Macromolecules, 2020 - ACS Publications
Ten years have passed since the conception of what was termed Lewis pair polymerization
(LPP) that employs Lewis acid and base in pairs to not only activate monomers but also …

Organic catalysis for ring-opening polymerization

AP Dove - 2012 - ACS Publications
Organic catalysis in ring-opening polymerization (ROP) has become a powerful alternative
to more traditional metal-based catalysts. The field has developed to a point at which there …

Hydrogen-bonding organocatalysts for ring-opening polymerization

C Thomas, B Bibal - Green Chemistry, 2014 - pubs.rsc.org
In the ring-opening polymerization (ROP) of cyclic esters and carbonates, hydrogen-bonding
organocatalysis offers an interesting alternative to metal-based and enzymatic catalysis to …

Recyclable and (Bio) degradable polyesters in a circular plastics economy

C Shi, EC Quinn, WT Diment, EYX Chen - Chemical Reviews, 2024 - ACS Publications
Polyesters carrying polar main-chain ester linkages exhibit distinct material properties for
diverse applications and thus play an important role in today's plastics economy. It is …

Carbon dioxide-based copolymers with various architectures

Y Li, YY Zhang, LF Hu, XH Zhang, BY Du… - Progress in Polymer …, 2018 - Elsevier
This review highlights recent advances in the synthesis of carbon dioxide (CO 2)-based
copolymers with both linear (di-, tri-, and multi-block, etc.) and non-linear (star-block and …