Switching of molecular spin states in inorganic complexes by temperature, pressure, magnetic field and light: towards molecular devices

A Bousseksou, G Molnár… - European Journal of …, 2004 - Wiley Online Library
The spin crossover phenomenon in molecular inorganic compounds is one of the most
spectacular examples of bistability phenomena leading to a switching between the high …

Established static models of spin crossover

J Pavlik, R Boča - European Journal of Inorganic Chemistry, 2013 - Wiley Online Library
Various models describing the stationary temperature‐induced phenomenon of spin
crossover in metal complexes are briefly discussed. The emphasis is put on the usability of …

Thermal hysteresis in spin-crossover compounds studied within the mechanoelastic model and its potential application to nanoparticles

L Stoleriu, P Chakraborty, A Hauser, A Stancu… - Physical Review B …, 2011 - APS
The recently developed mechanoelastic model is applied to characterize the thermal
transition in spin-crossover complexes, with special attention given to the case of spin …

Combined Experimental and Mechanoelastic Modeling Studies on the Low-Spin Stabilized Mixed Crystals of 3D Oxalate-Based Coordination Materials

M Dutta, S Bisht, P Ghosh, AI Chilug, D Mann… - Inorganic …, 2023 - ACS Publications
Structural studies involving single-crystal and powder X-ray diffraction analysis have been
performed on dehydrated coordination networks of the [Ni x Co1–x (bpy) 3][LiCr (ox) 3] …

Two-variable anharmonic model for spin-crossover solids: A like-spin domains interpretation

W Nicolazzi, S Pillet, C Lecomte - Physical Review B—Condensed Matter and …, 2008 - APS
Spin-crossover (SC) complexes are one of the most fascinating examples of molecular
bistability, whose solid-state properties are tightly connected to cooperative interactions …

Tutorial on the elastic theory of spin crossover materials

AI Popa, L Stoleriu, C Enachescu - Journal of Applied Physics, 2021 - pubs.aip.org
In this paper, we present the ingredients that allow the building-up of the elastic model, one
of the approaches that successfully describes the phenomena observed in complex spin …

Three-dimensional electroelastic modeling of the nucleation and propagation of the spin domains in spin-crossover materials

N Di Scala, NEI Belmouri, MAP Espejo… - Physical Review B, 2022 - APS
A three-dimensional version of the electroelastic model allowing the description of spin-
crossover (SCO) materials taking into account for the volume change at the transition …

[HTML][HTML] Elastic models, lattice dynamics and finite size effects in molecular spin crossover systems

C Enachescu, W Nicolazzi - Comptes Rendus Chimie, 2018 - Elsevier
The experimental studies of spin-crossover compounds switched in the last decade from
bulk measurements and macroscopic observations to the nanoscale and microscopic …

First-order reversal curve analysis of spin-transition thermal hysteresis in terms of physical-parameter distributions and their correlations

R Tanasa, C Enachescu, A Stancu, J Linares… - Physical Review B …, 2005 - APS
We investigate the thermal hysteresis of spin-crossover compounds by using the first-order
reversal curve (FORC) method. By magnetic measurements we have recorded the FORC …

Variation of the Cooperativity in Diluted Hofmann-Based Spin-Crossover Coordination Solids {Fe1–xMx(pz)[Pd(CN)4]}

C Das, S Dey, A Adak, C Enachescu… - Crystal Growth & …, 2023 - ACS Publications
This work is devoted to the investigation of the influence of dopants on the cooperativity of
3D Hofmann-based spin-crossover solids {Fe1–x M x (pz)[Pd (CN) 4]}, as reflected in the …