The functionalization of polymeric materials with Lewis acidic boron sites has led to exciting
new opportunities in diverse areas, ranging from new polymeric catalysts to the preparation …

A general method for copper-catalyzed arylation of sp2 C− H bonds with p K aʼs below 35
has been developed. The method employs aryl halide as the coupling partner, lithium …

Different preparative routes for the attachment of organoboron moieties to polyolefins and
applications of such materials are reviewed. Preparation from boron-functionalized …

Abstract Tris [tetrafluoro‐4‐(trifluoromethyl) phenyl] borane (BTolF) was prepared by treating
boron tribromide with tetrameric F3CC6F4‐CuI. The F3CC6F4‐CuI was generated from …

The bifunctional conjugated organoboranes Ar2B bt BAr2, which contain 2, 2 '-bithiophene
(bt) linkers and different aryl substituents on boron (3: Ar= pt BuC6H4; 4: Ar= C6F5; 5: Ar …

Luminescent B–N containing conjugated ladder compounds are prepared by directed
electrophilic aromatic substitution. Negishi cross-coupling reaction of 2, 7-dibromo-9, 9 …

Primary arylamines are an important unit broadly found in synthetic, biological, and
materials science. Herein we describe the development of a (NHC) Cu system that mediates …

An axially chiral dihydroborepine with a binaphthyl backbone and a C6F5 substituent at the
boron atom was prepared by transmetalation from the corresponding tin precursor. This …

We have developed a highly efficient new method for the introduction of Lewis acidic boron
centers into the side chains of organic polymers. Our methodology involves three steps:(i) …

A practical synthetic route for the preparation of the known bifunctional
perfluoroaryldiborane C6F4-1, 2-[B (C6F5) 2] 2, 1, and the new diborane C6F4-1, 2-[B …