When polymer chains are highly aligned: a perspective on extensional rheology

Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …

Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers

M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …

Some open challenges in polymer physics

GB McKenna, D Chen, SCH Mangalara… - Polymer Engineering …, 2022 - Wiley Online Library
Three subjects in polymer and soft matter physics are outlined in the present article. The first
relates to concepts of an ideal glass transition. We describe work on ultra‐stable glass …

Linear viscoelastic properties of putative cyclic polymers synthesized by reversible radical recombination polymerization (R3P)

D Chen, K Molnar, H Kim, CA Helfer, G Kaszas… - …, 2023 - ACS Publications
Linear viscoelastic properties in both melt and solution states are reported for a series of
poly (3, 6-dioxa-1, 8-octanedithiol)(polyDODT) made by reversible radical recombination …

[HTML][HTML] Composite entanglement topology and extensional rheology of symmetric ring-linear polymer blends

TC O'Connor, T Ge, GS Grest - Journal of Rheology, 2022 - pubs.aip.org
Extensive molecular simulations are applied to characterize the equilibrium dynamics,
entanglement topology, and nonlinear extensional rheology of symmetric ring-linear …

Topology-Based Detection and Tracking of Deadlocks Reveal Aging of Active Ring Melts

C Micheletti, I Chubak, E Orlandini, J Smrek - ACS Macro Letters, 2024 - ACS Publications
Connecting the viscoelastic behavior of stressed ring melts to the various forms of
entanglement that can emerge in such systems is still an open challenge. Here, we consider …

To thread or not to thread? Effective potentials and threading interactions between asymmetric ring polymers

R Staňo, CN Likos, J Smrek - Soft Matter, 2023 - pubs.rsc.org
We use computer simulations to study a system of two unlinked ring polymers, whose length
and bending stiffness are systematically varied. We derive the effective potentials between …

Optical-Tweezers-integrating-Differential-Dynamic-Microscopy maps the spatiotemporal propagation of nonlinear strains in polymer blends and composites

KR Peddireddy, R Clairmont, P Neill, R McGorty… - Nature …, 2022 - nature.com
How local stresses propagate through polymeric fluids, and, more generally, how
macromolecular dynamics give rise to viscoelasticity are open questions vital to wide …

Interfacial behaviors of giant amphiphilic molecules composed of hydrophobic isobutyl poss and hydrophilic poss bearing carboxylic acid groups at the air–water …

W Wang, X Xu, F Feng, Y Shao, H Jian, H Liu… - Langmuir, 2023 - ACS Publications
The behavior of giant amphiphilic molecules at the air–water interface has become a subject
of concern to researchers. Small changes in the molecular structure can cause obvious …

Mixing linear polymers with rings and catenanes: Bulk and interfacial behavior

R Staňo, CN Likos, SA Egorov - Macromolecules, 2023 - ACS Publications
We derive and parameterize effective interaction potentials between a multitude of different
types of ring polymers and linear chains, varying the bending rigidity and solvent quality for …