Photocatalytic Systems for CO2 Reduction: Metal-Complex Photocatalysts and Their Hybrids with Photofunctional Solid Materials

H Kumagai, Y Tamaki, O Ishitani - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Photocatalytic CO2 reduction is a critical objective in the field of artificial
photosynthesis because it can potentially make a total solution for global warming and …

Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties

J Yuan, Z Xu, MO Wolf - Chemical Science, 2022 - pubs.rsc.org
The use of a heteroatom, such as sulfur, as a linker or bridge, in π-conjugated materials has
advantages over purely carbon-based ones due to the accessibility of higher oxidation …

Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer

Y Wang, T Liu, L Chen, D Chao - Inorganic Chemistry, 2021 - ACS Publications
Photocatalytic CO2 reduction reaction is believed to be a promising approach for CO2
utilization. In this work, a noble metal-free photocatalytic system, composed of bis …

Tracking Charge Accumulation in a Functional Triazole‐Linked Ruthenium‐Rhenium Dyad Towards Photocatalytic Carbon Dioxide Reduction

P Gotico, TT Tran, A Baron, B Vauzeilles… - …, 2021 - Wiley Online Library
Abstract The [Re (bpy)(CO) 3Cl] catalyst pioneered by Lehn for the two‐electron reduction of
CO2 has constantly revealed unique facets in the mechanistic understanding of the selective …

Rhenium (I) Complexes with Sulfur-Bridged Dipyridyl Ligands: Structural, Photophysical, and Computational Studies

KM Tong, J Toigo, BO Patrick, MO Wolf - Inorganic Chemistry, 2023 - ACS Publications
A series of six new rhenium (I) tricarbonyl complexes [Re (CO) 3 (N–N) Br] bearing sulfur-
bridged dipyridyl (N–N) ligands with three different oxidation states (sulfide (S), sulfoxide …

Heterobinuclear Metallocomplexes as Photocatalysts in Organic Synthesis

VA Ionova, AS Abel, AD Averin, IP Beletskaya - Catalysts, 2023 - mdpi.com
Photocatalytic processes under visible light have constantly been finding more and more
applications in organic synthesis as they allow a wide range of transformations to proceed …

Highly Robust Rhenium(I) Bipyridyl Complexes Containing Dipyrromethene‐BF2 Chromophores for Visible Light‐Driven CO2 Reduction

LQ Qiu, ZW Yang, X Yao, XY Li, LN He - ChemSusChem, 2022 - Wiley Online Library
New rhenium bipyridyl complexes with dipyrromethene‐BF2 chromophores (A‐ReBDP‐CZ,
A‐ReBDP2, ReBDP‐CZ, and ReBDP2) were developed for highly efficient photocatalytic …

Coupling Waste Plastic Upgrading and CO2 Photoreduction to High-Value Chemicals by a Binuclear Re–Ru Heterogeneous Catalyst

M Li, S Zhang - ACS Catalysis, 2024 - ACS Publications
Photocatalytically converting waste plastic to high-value chemicals is an energy-efficient and
promising approach. Nonetheless, the limited photocatalytic efficiency due to the extremely …