Organolithium compounds have been at the forefront of synthetic chemistry for over a
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …

Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

The polarity of a radical intermediate profoundly impacts its reactivity and selectivity. To
quantify this influence and predict its effects, the electrophilicity/nucleophilicity of> 500 …

The construction of C (sp3)–Si bonds is important in synthetic, medicinal, and materials
chemistry. In this context, reactions mediated by silyl radicals have become increasingly …

Cross-coupling of two alkyl fragments is an efficient method to produce organic molecules
rich in sp 3-hybridized carbon centres, which are attractive candidate compounds in drug …

The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

C–H functionalization is a very active research field that has attracted the interest of
scientists from many disciplines. This Outlook describes the collaborative efforts within the …

We report the use of electrochemistry to perform a direct oxidative dearomatization of
indoles leading to 2, 3-dialkoxy or 2, 3-diazido indolines under undivided conditions at a …

The development of efficient and sustainable methods for hydrosilane and hydrogermane
functionalization is of importance due to their abundant use as functional modifiers and high …

Silicon-containing molecules are of great academic and industrial interest with widespread
applications in several research areas such as materials science, medicinal chemistry, and …