Surface chemistry and catalysis confined under two-dimensional materials

Q Fu, X Bao - Chemical Society Reviews, 2017 - pubs.rsc.org
Two-dimensional (2D) materials are characterised by their strong intraplanar bonding but
weak interplanar interaction. Interfaces between neighboring 2D layers or between 2D …

Graphene growth and properties on metal substrates

Y Dedkov, E Voloshina - Journal of Physics: Condensed Matter, 2015 - iopscience.iop.org
Graphene–metal interface as one of the interesting graphene-based objects attracts much
attention from both application and fundamental science points of view. This paper gives a …

Confined catalysis under two-dimensional materials

H Li, J Xiao, Q Fu, X Bao - Proceedings of the National …, 2017 - National Acad Sciences
Confined microenvironments formed in heterogeneous catalysts have recently been
recognized as equally important as catalytically active sites. Understanding the …

Carbon Encapsulation of Supported Metallic Iridium Nanoparticles: An in Situ Transmission Electron Microscopy Study and Implications for Hydrogen Evolution …

P Liu, A Klyushin, P Chandramathy Surendran… - ACS …, 2023 - ACS Publications
Carbon-supported metal nanoparticles (NPs) comprise an important class of heterogeneous
catalysts. The interaction between the metal and carbon support influences the overall …

Graphene cover-promoted metal-catalyzed reactions

Y Yao, Q Fu, YY Zhang, X Weng, H Li… - Proceedings of the …, 2014 - National Acad Sciences
Graphitic overlayers on metals have commonly been considered as inhibitors for surface
reactions due to their chemical inertness and physical blockage of surface active sites. In …

A nickel nanocatalyst within a h-BN shell for enhanced hydrogen oxidation reactions

L Gao, Y Wang, H Li, Q Li, N Ta, L Zhuang, Q Fu… - Chemical …, 2017 - pubs.rsc.org
The development of low-cost and high-performance electrocatalysts remains a challenge for
the hydrogen oxidation reaction (HOR) in alkaline membrane fuel cells. Here, we have …

Hexagonal boron nitride cover on Pt (111): a new route to tune molecule–metal interaction and metal-catalyzed reactions

Y Zhang, X Weng, H Li, H Li, M Wei, J Xiao, Z Liu… - Nano …, 2015 - ACS Publications
In heterogeneous catalysis molecule–metal interaction is often modulated through structural
modifications at the surface or under the surface of the metal catalyst. Here, we suggest an …

Elucidating the mechanism of large phosphate molecule intercalation through graphene-substrate Heterointerfaces

J Liang, K Ma, X Zhao, G Lu, J Riffle… - … Applied Materials & …, 2023 - ACS Publications
Intercalation is the process of inserting chemical species into the heterointerfaces of two-
dimensional (2D) layered materials. While much research has focused on the intercalation …

Reverse water–gas shift or Sabatier methanation on Ni (110)? Stable surface species at near-ambient pressure

M Roiaz, E Monachino, C Dri, M Greiner… - Journal of the …, 2016 - ACS Publications
The interaction of CO, CO2, CO+ H2, CO2+ H2, and CO+ CO2+ H2 with the nickel (110)
single crystal termination has been investigated at 10–1 mbar in situ as a function of the …

The influence of intercalated oxygen on the properties of graphene on polycrystalline Cu under various environmental conditions

R Blume, PR Kidambi, BC Bayer… - Physical Chemistry …, 2014 - pubs.rsc.org
Intercalation of oxygen at the interface of graphene grown by chemical vapour deposition
and its polycrystalline copper catalyst can have a strong impact on the electronic, chemical …