Autocatalysis: Kinetics, mechanisms and design

AI Hanopolskyi, VA Smaliak, AI Novichkov… - …, 2021 - Wiley Online Library
The importance of autocatalysis spans from practical applications such as in chemically
amplified photoresists, to autocatalysis playing a fundamental role in evolution as well as a …

Recent advances in isoxazole chemistry

AV Galenko, AF Khlebnikov, MS Novikov… - Russian Chemical …, 2015 - iopscience.iop.org
The preparation methods and reactions of isoxazoles are described and systematized on
the basis of analysis of the literature published from 2005 to present. In the discussion of …

Versatile synthesis of metal-compound based mesoporous Janus nanoparticles

Y Yu, R Lin, H Yu, M Liu, E Xing, W Wang… - Nature …, 2023 - nature.com
The construction of mesoporous Janus nanoparticles (mJNPs) with controllable components
is of great significance for the development of sophisticated nanomaterials with …

Synergistic noncovalent catalysis facilitates base-free Michael addition

J Wang, TA Young, F Duarte… - Journal of the American …, 2020 - ACS Publications
Carbon–carbon bond-forming processes that involve the deprotonation of a weakly acidic C–
H pro-nucleophile using a strong Brønsted base are central to synthetic methodology …

Primary nitro compounds: Progress in the synthesis of isoxazoles by condensation with aldehydes or activated ketones

F De Sarlo, F Machetti - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Among known strategies directed to the synthesis of isoxazole derivatives reactions of
aldehydes with primary nitro compounds deserve a comprehensive treatment, including the …

Regioselective synthesis of isoxazole and 1, 2, 4-oxadiazole-derived phosphonates via [3+ 2] cycloaddition

BA Chalyk, AS Sosedko, DM Volochnyuk… - Organic & …, 2018 - pubs.rsc.org
The results of the study on reactions of halogenoximes bearing (protected) functional groups
or fluorinated substituents with various phosphorus-containing dipolarophiles are described …

Harnessing the TEMPO-catalyzed aerobic oxidation for Machetti–De Sarlo reaction toward sustainable synthesis of isoxazole libraries

M Vadivelu, S Sampath, K Muthu… - The Journal of …, 2019 - ACS Publications
A practical synthesis of isoxazole/isoxazoline derivatives via Machetti–De Sarlo reaction
under sustainable conditions has been accomplished. This protocol involves the use of …

Effect of Aqueous Polyethylene Glycol on 1, 3‐Dipolar Cycloaddition of Benzoylnitromethane/Ethyl 2‐Nitroacetate with Dipolarophiles: Green Synthesis of Isoxazoles …

R Gangadhara Chary… - Advanced Synthesis …, 2014 - Wiley Online Library
Abstract A 1: 1 mixture of water‐polyethylene glycol (PEG) facilitated the 1, 3‐dipolar
cycloaddition of benzoylnitromethane/ethyl 2‐nitroacetate with terminal alkynes or alkenes …

Reductive Recyclization of sp3-Enriched Functionalized Isoxazolines into α-Hydroxy Lactams

BA Chalyk, AV Khutorianskyi… - The Journal of …, 2021 - ACS Publications
An efficient synthesis (up to a 200 g scale) of 3-hydroxypyrrolidin-2-ones bearing alkyl
substituents or functional groups at the C-5 position is described. The reaction sequence …

Mechanistic rationalization of unusual sigmoidal kinetic profiles in the Machetti–De Sarlo cycloaddition reaction

MP Mower, DG Blackmond - Journal of the American Chemical …, 2015 - ACS Publications
Unusual sigmoidal kinetic profiles in the Machetti–De Sarlo base-catalyzed 1, 3-dipolar
cycloaddition of acrylamide to N-methylnitroacetamide are rationalized by detailed in situ …