Where chemocatalysis meets biocatalysis: In water

H Gröger, F Gallou, BH Lipshutz - Chemical Reviews, 2022 - ACS Publications
Chemoenzymatic catalysis, by definition, involves the merging of sequential reactions using
both chemocatalysis and biocatalysis, typically in a single reaction vessel. A major …

Expanding the synthetic toolbox through metal–enzyme cascade reactions

S González-Granda, J Albarrán-Velo… - Chemical …, 2023 - ACS Publications
The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …

Asymmetric hydrogenation catalyzed by first-row transition metal complexes

J Wen, F Wang, X Zhang - Chemical Society Reviews, 2021 - pubs.rsc.org
This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …

Opportunities and challenges for combining chemo-and biocatalysis

F Rudroff, MD Mihovilovic, H Gröger, R Snajdrova… - Nature Catalysis, 2018 - nature.com
The past decade has seen a substantial increase in successful examples of the combination
of chemo-and biocatalysis for multistep syntheses. This is driven by obvious advantages …

Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines

O Verho, JE Bäckvall - Journal of the American Chemical …, 2015 - ACS Publications
Chemoenzymatic dynamic kinetic resolution (DKR) constitutes a convenient and efficient
method to access enantiomerically pure alcohol and amine derivatives. This Perspective …

One-pot chemo-and photo-enzymatic linear cascade processes

JM Carceller, KS Arias, MJ Climent, S Iborra… - Chemical Society …, 2024 - pubs.rsc.org
The combination of chemo-and photocatalyses with biocatalysis, which couples the flexible
reactivity of the photo-and chemocatalysts with the highly selective and environmentally …

[PDF][PDF] Green Chemistry and Catalysis

RA Sheldon - 2007 - 117.250.119.200
This first book to focus on catalytic processes from the viewpoint of green chemistry presents
every important aspect:? Numerous catalytic reductions and oxidations methods? Solid-acid …

Industrial methods for the production of optically active intermediates

M Breuer, K Ditrich, T Habicher, B Hauer… - Angewandte Chemie …, 2004 - Wiley Online Library
Enantiomerically pure amino acids, amino alcohols, amines, alcohols, and epoxides play an
increasingly important role as intermediates in the pharmaceutical industry and …

Concurrent tandem catalysis

JC Wasilke, SJ Obrey, RT Baker, GC Bazan - Chemical reviews, 2005 - ACS Publications
The replacement of multistep, salt-generating chemical synthesis with efficient catalyzed
reactions that strive for atom economy1 is having a significant impact on the manufacture of …

Borrowing hydrogen in the activation of alcohols

MHSA Hamid, PA Slatford… - Advanced Synthesis & …, 2007 - Wiley Online Library
Alcohols can be temporarily converted into carbonyl compounds by the metal‐catalysed
removal of hydrogen. The carbonyl compounds are reactive in a wider range of …