We report a mild, catalytic method for the intermolecular reductive coupling of feedstock
dienes and styrenes with ketones. Our conditions allow concomitant formation of a cobalt …

An iron/chromium system (Fe (OAc) 2, CpCr (CO) 3H) catalyzes the preparation of β, γ-or γ,
δ-unsaturated amides from 1, 4, 2-dioxazol-5-ones. An acyl nitrenoid iron complex seems …

Access to γ-functionalized amides represents a challenge in organic synthesis. The recent
upsurge of biomimetic metal nitrenoid-mediated C–H functionalization offers a method for …

Intramolecular hydroarylation of alkenes through hydrogen atom transfer (HAT) represents a
robust method to prepare benzo-fused heterocycles. However, the reported methods have …

In metal hydride-catalyzed alkene hydrofunctionalization reactions via hydrogen atom
transfer, simple carbonyl groups have been well-recognized as good somophiles at the …

Catalytic isomerization of alkenes is a highly atom-economical approach to upgrade from
lower-to higher-value alkenes. Consequently, tremendous attention has been devoted to the …

A hydroxyl‐assisted, organophotoredox/cobalt dual catalyzed annulation of 2‐
propynolphenols to form 2‐hydroxymethyl‐benzo [b] furans was developed by employing 1 …

The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes,
employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII …

Carbon‐centered radicals can be stabilized by delocalization of their spin density into the
vacant p orbital of a boron substituent. α‐Vinyl boronates, in particular pinacol (Bpin) …

Wir berichten über eine milde, katalytische Methode für die intermolekulare reduktive
Kopplung von Dienen und Styrolen mit Ketonen. Unsere Bedingungen ermöglichen die …