Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Porphyrins as catalysts in scalable organic reactions

JC Barona-Castaño, CC Carmona-Vargas… - Molecules, 2016 - mdpi.com
Catalysis is a topic of continuous interest since it was discovered in chemistry centuries ago.
Aiming at the advance of reactions for efficient processes, a number of approaches have …

Chemical reactions catalyzed by metalloporphyrin-based metal-organic frameworks

S Nakagaki, GKB Ferreira, GM Ucoski… - Molecules, 2013 - mdpi.com
The synthetic versatility and the potential application of metalloporphyrins (MP) in different
fields have aroused researchers' interest in studying these complexes, in an attempt to …

Metalloporphyrins immobilized on silica-coated Fe3O4 nanoparticles: Magnetically recoverable catalysts for the oxidation of organic substrates

GM Ucoski, FS Nunes, G DeFreitas-Silva… - Applied Catalysis A …, 2013 - Elsevier
In this paper we report the immobilization of different cationic and neutral metalloporphyrins
(MPs) on silica-coated Fe3O4 nanoparticles, obtained by basic hydrolytic sol–gel process …

Mn porphyrins immobilized on non-modified and chloropropyl-functionalized mesoporous silica SBA-15 as catalysts for cyclohexane oxidation

VHA Pinto, JS Reboucas, GM Ucoski… - Applied Catalysis A …, 2016 - Elsevier
In this work, solid catalysts were prepared by the heterogenization of Mn porphyrins (MnP)
on mesoporous silica SBA-15 by two simple strategies:(1) immobilization of the three …

Iron catalysis for in situ regeneration of oxidized cofactors by activation and reduction of molecular oxygen: a synthetic metalloporphyrin as a biomimetic NAD (P) H …

H Maid, P Böhm, SM Huber, W Bauer… - Angewandte Chemie …, 2011 - Wiley Online Library
A major challenge in biomimetic catalysis is the development of synthetic low-molecular-
weight compounds that are able to mimic the catalytic function of enzymes.[1a] Thus …

Efficient atrazine degradation catalyzed by manganese porphyrins: determination of atrazine degradation products and their toxicity evaluation by human blood cells …

ALA Lage, JM Ribeiro, EM de Souza-Fagundes… - Journal of hazardous …, 2019 - Elsevier
Atrazine (ATZ) is an herbicide that has been considered an environmental pollutant
worldwide. ATZ contaminates groundwaters and can persist in soils for up to a year causing …

New highly brominated Mn-porphyrin: a good catalyst for activation of inert C–H bonds

VS da Silva, S Nakagaki, GM Ucoski, YM Idemori… - RSC …, 2015 - pubs.rsc.org
This work describes the synthesis and characterization of a novel third-generation catalyst 5,
10, 15, 20-tetrakis-(4′-bromine-3′, 5′-dimethoxyphenyl)-2, 3, 7, 8, 12, 13, 17, 18 …

Biomimetic oxidation of cyclic and linear alkanes: high alcohol selectivity promoted by a novel manganese porphyrin catalyst

VS da Silva, WC dos Santos Vieira… - New Journal of …, 2017 - pubs.rsc.org
A novel third-generation metalloporphyrin, chloro-5, 10, 15, 20-tetrakis-(3′-bromine-4′-
methoxyphenyl)-2, 3, 7, 8, 12, 13, 17, 18-octabromoporphyrinatomanganese …

Effect of imidazole on biomimetic cyclohexane oxidation by first-, second-, and third-generation manganese porphyrins using PhIO and PhI (OAc) 2 as oxidants

VS da Silva, AM Meireles, DC da Silva Martins… - Applied Catalysis A …, 2015 - Elsevier
In this work, spectrophotometric titrations of first-(Mn III TPPCl), second-(Mn III APTPPCl and
Mn III T4CMPPCl), and third-(Mn III Br 9 APTPPCl and Mn III Br 8 T4CMPPCl) generation …