Metal substitution of molecular sieve systems is a major driving force in developing novel
catalytic processes to meet current demands of green chemistry concepts and to achieve …

Heterogeneous catalysts undergo thermal-and/or adsorbate-induced dynamic changes
under reaction conditions, which consequently modify their catalytic behavior. Hence, it is …

Abstract Titanium silicalite-1 (TS-1) is a zeolitic material with MFI framework structure, in
which 1 to 2 per cent of the silicon atoms are substituted for titanium atoms. It is widely used …

Abstract Hydrogen peroxide (H2O2) is a highly effective, green oxidant that has found
application in sectors ranging from the synthesis of fine chemicals and waste stream …

Propylene epoxidation with H2 and O2 to propylene oxide (PO) is a very valuable reaction.
Considering the precious gold catalysts commonly used in the current research, the design …

The modulation and determination of the coordination environments of Ti active sites in
titanosilicate zeolites are key challenges in the rational design of high-performance …

Lewis acidic Snβ zeolites have emerged as highly interesting catalysts for a variety of
biomass-related reactions. During the last decades, a vast body of research has focused on …

Although Ziegler–Natta (ZN) catalysts play a major role in the polyolefin market, a true
understanding of their properties at the molecular level is still missing. In particular, there is a …

The distribution of titanium (Ti) active sites in the framework of TS-1 zeolite is one of the
critical factors affecting its catalytic performance, since it can influence accessibility of the Ti …

One-pot hydrothermal method was adopted to synthesize Pd catalysts encapsulated by TS-1
zeolites [Pd@ TS-1 (x)]. The strategy could effectively improve Pd dispersion and reduce the …