Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

Recent development in transition metal-catalysed C–H olefination

W Ali, G Prakash, D Maiti - Chemical Science, 2021 - pubs.rsc.org
Transition metal-catalysed functionalizations of inert C–H bonds to construct C–C bonds
represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

W Ma, P Gandeepan, J Li, L Ackermann - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
The transition metal-catalyzed transformation of otherwise inert C–H bonds into substituted
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …

Remote para-C–H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly

S Bag, T Patra, A Modak, A Deb, S Maity… - Journal of the …, 2015 - ACS Publications
Site-selective C–H functionalization has emerged as an efficient tool in simplifying the
synthesis of complex molecules. Most often, directing group (DG)-assisted metallacycle …

Rhodium-catalyzed C–H activation of phenacyl ammonium salts assisted by an oxidizing C–N bond: a combination of experimental and theoretical studies

S Yu, S Liu, Y Lan, B Wan, X Li - Journal of the American …, 2015 - ACS Publications
Rh (III)-catalyzed C–H activation assisted by an oxidizing directing group has evolved to a
mild and redox-economic strategy for the construction of heterocycles. Despite the success …

Palladium(II)‐Catalyzed meta‐CH Olefination: Constructing Multisubstituted Arenes through Homo‐Diolefination and Sequential Hetero‐Diolefination

M Bera, A Maji, SK Sahoo… - Angewandte Chemie …, 2015 - Wiley Online Library
Divinylbenzene derivatives represent an important class of molecular building blocks in
organic chemistry and materials science. Reported herein is the palladium‐catalyzed …

Switch to allylic selectivity in cobalt-catalyzed dehydrogenative Heck reactions with unbiased aliphatic olefins

S Maity, R Kancherla, U Dhawa, E Hoque… - ACS …, 2016 - ACS Publications
A unique C–H allylation has been discovered with unbiased aliphatic olefins. An intimate M–
L affiliation between a high-valent cobalt catalyst and amino-quinoline derived benzamides …

C (alkenyl)–H activation via six-membered palladacycles: catalytic 1, 3-diene synthesis

M Liu, P Yang, MK Karunananda, Y Wang… - Journal of the …, 2018 - ACS Publications
A catalytic method to prepare highly substituted 1, 3-dienes from two different alkenes is
described using a directed, palladium (II)-mediated C (alkenyl)–H activation strategy. The …

Palladium catalysed meta-C–H functionalization reactions

A Dey, S Agasti, D Maiti - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
The directing group assisted site selective C–H functionalization approach is having a
continuous impact in the field of natural product synthesis, drug discovery and material …