Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
Dihalomethanes as bent bifunctional XB/XB‐Donating building blocks for construction of metal‐involving halogen bonded hexagons
MV Kashina, MA Kinzhalov, AS Smirnov… - Chemistry–An Asian …, 2019 - Wiley Online Library
Abstract The dihalomethanes CH2X2 (X= Cl, Br, I) were co‐crystallized with the isocyanide
complexes trans‐[MXM2 (CNC6H4‐4‐XC) 2](M= Pd, Pt; XM= Br, I; XC= F, Cl, Br) to give an …
complexes trans‐[MXM2 (CNC6H4‐4‐XC) 2](M= Pd, Pt; XM= Br, I; XC= F, Cl, Br) to give an …
Pt/Pd and I/Br isostructural exchange provides formation of C–I··· Pd, C–Br··· Pt, and C–Br··· Pd metal-involving halogen bonding
Complexes trans-[MCl2 (NCNMe2) 2](M= Pt 1, Pd 2) were cocrystallized with CHBr3 and
CHI3, forming 1: 2 adducts isomorphic with previously reported trans-[PtCl2 (NCNMe2) 2] …
CHI3, forming 1: 2 adducts isomorphic with previously reported trans-[PtCl2 (NCNMe2) 2] …
Halobismuthates with halopyridinium cations: Appearance or non-appearance of unusual colouring
A series of chloro-and bromobismuthate complexes with bromopyridinium cations was
prepared and characterized by XRD analysis and diffuse reflectance spectroscopy. In one …
prepared and characterized by XRD analysis and diffuse reflectance spectroscopy. In one …
Halogen Contacts‐Induced Unusual Coloring in BiIII Bromide Complex: Anion‐to‐Cation Charge Transfer via Br⋅⋅⋅Br Interactions
SA Adonin, ID Gorokh, AS Novikov… - … A European Journal, 2017 - Wiley Online Library
Abstract A yellow bromobismuthate {(2‐BrPy) 2H}[BiBr4](1, 2‐BrPy= 2‐bromopyridinium)
transforms into the unusually deeply colored cherry‐red (2‐BrPyH) 2 [BiBr5](2). A …
transforms into the unusually deeply colored cherry‐red (2‐BrPyH) 2 [BiBr5](2). A …
Bromo‐and polybromoantimonates (V): structural and theoretical studies of hybrid halogen‐rich halometalate frameworks
SA Adonin, MA Bondarenko… - … A European Journal, 2018 - Wiley Online Library
Abstract Cation‐dependent reactions “[SbBr6] 3−+ Br2+ HBr+ CationBrx” result in the
formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional …
formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional …
Halogen bonding-assisted assembly of bromoantimonate (v) and polybromide-bromoantimonate-based frameworks
SA Adonin, MA Bondarenko, AS Novikov… - …, 2019 - pubs.rsc.org
In the reactions between the mononuclear [SbBr6] 3− species, Br2 and various {cationBr}
salts, Sb (III) is commonly oxidized to Sb (V), and the cations play a key role in the formation …
salts, Sb (III) is commonly oxidized to Sb (V), and the cations play a key role in the formation …
Ligation-enhanced π-hole··· π interactions involving isocyanides: Effect of π-hole··· π noncovalent bonding on conformational stabilization of acyclic diaminocarbene …
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with the aminoazoles [1 H-
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
One-dimensional polymeric polybromotellurates (IV): Structural and theoretical insights into halogen⋯ halogen contacts
AN Usoltsev, SA Adonin, AS Novikov… - …, 2017 - pubs.rsc.org
Reactions of TeO2 and Br2 in concentrated HBr in the presence of various organic cations
resulted in the formation of one-dimensional supramolecular polymers with the structure …
resulted in the formation of one-dimensional supramolecular polymers with the structure …
Studies of Nature of Uncommon Bifurcated I–I···(I–M) Metal-Involving Noncovalent Interaction in Palladium (II) and Platinum (II) Isocyanide Cocrystals
M Bulatova, DM Ivanov, JM Rautiainen… - Inorganic …, 2021 - ACS Publications
Two isostructural trans-[MI2 (CNXyl) 2]· I2 (M= Pd or Pt; CNXyl= 2, 6-dimethylphenyl
isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal …
isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal …