Design and construction of on-surface molecular nanoarchitectures: lessons and trends from trimesic acid and other small carboxlyated building blocks

J MacLeod - Journal of Physics D: Applied Physics, 2019 - iopscience.iop.org
Molecular self-assembly and reactions at surfaces provide a versatile and appealing
approach to nanomaterials synthesis, with a tremendous potential for engineering purpose …

Surface supramolecular assemblies tailored by chemical/physical and synergistic stimuli: a scanning tunneling microscopy study

S Sahare, P Ghoderao, Y Chan, SL Lee - Nanoscale, 2023 - pubs.rsc.org
Supramolecular self-assemblies formed by various non-covalent interactions can produce
diverse functional networks on solid surfaces. These networks have recently attracted much …

Local conformational switching of supramolecular networks at the solid/liquid interface

FP Cometto, K Kern, M Lingenfelder - ACS nano, 2015 - ACS Publications
We use the electric field in a scanning tunneling microscope to manipulate the transition
between open and close packed 2D supramolecular networks of neutral molecules in …

Reactive force field-based molecular dynamics simulations on the thermal stability of trimesic acid on graphene: implications for the design of supramolecular …

DK Jacquelín, FA Soria… - ACS Applied Nano …, 2021 - ACS Publications
In this work, we used the ReaxFF force field to investigate the dynamics of different network
structures of trimesic acid (TMA) molecules on graphene as a function of temperature. We …

Substrate effects in the supramolecular assembly of 1, 3, 5-benzene tricarboxylic acid on graphite and graphene

JM MacLeod, JA Lipton-Duffin, D Cui, S De Feyter… - Langmuir, 2015 - ACS Publications
The behavior of small molecules on a surface depends critically on both molecule–substrate
and intermolecular interactions. We present here a detailed comparative investigation of 1 …

Electronic Decoupling in C3-Symmetrical Light-Responsive Tris(Azobenzene) Scaffolds: Self-Assembly and Multiphotochromism

A Galanti, V Diez-Cabanes, J Santoro… - Journal of the …, 2018 - ACS Publications
We report the synthesis of a novel C3-symmetrical multiphotochromic molecule bearing
three azobenzene units at positions 1, 3, 5 of the central phenyl ring. The unique …

Origin of Solvent-Induced Polymorphism in Self-Assembly of Trimesic Acid Monolayers at Solid–Liquid Interfaces

O Ochs, M Hocke, S Spitzer, WM Heckl… - Chemistry of …, 2020 - ACS Publications
Encoding information in the chemical structure of tectons is the pivotal strategy in self-
assembly for the realization of targeted supramolecular structures. However, frequently …

Polymorphism driven by concentration at the solid–liquid interface

N Thi Ngoc Ha, TG Gopakumar… - The Journal of Physical …, 2011 - ACS Publications
Self-assembly at the liquid–solid interface is controlled by concentration of solute in solvent.
Trimesic acid (TMA) dissolved in fatty acids shows a polymorphism on HOPG surface tuned …

Role of substrate in directing the self-assembly of multicomponent supramolecular networks at the liquid–solid interface

T Balandina, K Tahara, N Sändig, MO Blunt… - ACS …, 2012 - ACS Publications
The self-assembly of multicomponent networks at the liquid–solid interface between Au
(111) or highly oriented pyrolytic graphite (HOPG) and organic solvents was investigated …

Synergic effect: Temperature-assisted electric-field-induced supramolecular phase transitions at the liquid/solid interface

A Mahmood, M Saeed, Y Chan, AS Saleemi, J Guo… - Langmuir, 2019 - ACS Publications
Using trimesic acid (TMA) as a model system by means of scanning tunneling microscope
(STM) equipped with a temperature controller, here, we report a temperature-assisted …