Reactions and polymerizations at the liquid–liquid interface

K Piradashvili, EM Alexandrino, FR Wurm… - Chemical …, 2016 - ACS Publications
Reactions and polymerizations at the interface of two immiscible liquids are reviewed. The
confinement of two reactants at the interface to form a new product can be advantageous in …

[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Direct imaging of micrometer-thick interfaces in salt–salt aqueous biphasic systems

D Degoulange, R Pandya… - Proceedings of the …, 2023 - National Acad Sciences
Unlike the interface between two immiscible electrolyte solutions (ITIES) formed between
water and polar solvents, molecular understanding of the liquid–liquid interface formed for …

Applications of nanopipettes in the analytical sciences

CA Morris, AK Friedman, LA Baker - Analyst, 2010 - pubs.rsc.org
In this review, we describe measurements and applications of interest to the analytical
community that makes use of simple nanopipettes. Fabricated by applying heat during the …

Discrete Helmholtz model: a single layer of correlated counter-ions. Metal oxides and silica interfaces, ion-exchange and biological membranes

GC Gschwend, HH Girault - Chemical Science, 2020 - pubs.rsc.org
The mechanism by which interfaces in solution can be polarised depends on the nature of
the charge carriers. In the case of a conductor, the charge carriers are electrons and the …

Structure and reactivity of the polarised liquid–liquid interface: what we know and what we do not

GC Gschwend, A Olaya, P Peljo, HH Girault - Current Opinion in …, 2020 - Elsevier
Charge transfer phenomena at the interface between two immiscible electrolyte solutions
(ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature …

Kinetic study of rapid transfer of tetraethylammonium at the 1, 2-dichloroethane/water interface by nanopipet voltammetry of common ions

Y Wang, J Velmurugan, MV Mirkin, PJ Rodgers… - Analytical …, 2010 - ACS Publications
Steady-state voltammetry at the pipet-supported liquid/liquid interface has previously been
used to measure kinetics of simple and facilitated ion transfer (IT) processes. Recently, we …

Free Energy for the Permeation of Na+ and Cl Ions and Their Ion-Pair through a Zwitterionic Dimyristoyl Phosphatidylcholine Lipid Bilayer by Umbrella Integration …

IV Khavrutskii, AA Gorfe, B Lu… - Journal of the American …, 2009 - ACS Publications
Understanding the mechanism of ion permeation across lipid bilayers is key to controlling
osmotic pressure and developing new ways of delivering charged, drug-like molecules …

Electrochemical sensing and imaging based on ion transfer at liquid/liquid interfaces

S Amemiya, J Kim, A Izadyar, B Kabagambe, M Shen… - Electrochimica …, 2013 - Elsevier
Here we review the recent applications of ion transfer (IT) at the interface between two
immiscible electrolyte solutions (ITIES) for electrochemical sensing and imaging. In …

Reaction dynamics at liquid interfaces

I Benjamin - Annual review of physical chemistry, 2015 - annualreviews.org
The liquid interface is a narrow, highly anisotropic region, characterized by rapidly varying
density, polarity, and molecular structure. I review several aspects of interfacial solvation and …