Remarkably boosting ethanol upgrading to higher alcohols through cooperative catalysis of surface-interface multiple-active sites on nitrogen-doped carbon …

L Yuan, M Zhang, G Fan, F Li - Applied Catalysis B: Environmental, 2024 - Elsevier
Upgrading biomass-derived ethanol to higher alcohols is a significantly promising process
involving multi-step tandem reactions finely regulated by multiple active sites. However, the …

Hydrogenolysis of organosolv lignin in ethanol/isopropanol media without added transition-metal catalyst

C Cheng, J Truong, JA Barrett, D Shen… - ACS Sustainable …, 2019 - ACS Publications
Lignin is the largest renewable source of aromatic chemical building blocks on the planet
and has great potential for the production of value-added chemicals. Herein, we describe …

Active and stable Cu doped NiMgAlO catalysts for upgrading ethanol to n-butanol

Z Wang, M Yin, J Pang, X Li, Y Xing, Y Su, S Liu… - Journal of Energy …, 2022 - Elsevier
Upgrading ethanol to n-butanol is an attractive way for renewable n-butanol production.
Herein, Cu was selected to modify NiMgAlO catalysts for improving ethanol conversion and …

Condensed-phase ethanol conversion to higher alcohols over bimetallic catalysts

I Nezam, J Zak, DJ Miller - Industrial & Engineering Chemistry …, 2020 - ACS Publications
The catalytic condensation of ethanol to n-butanol and higher alcohols, known collectively
as Guerbet reactions, has attracted attention in recent years as ethanol becomes …

The lignin challenge in catalytic conversion of biomass solids to chemicals and fuels

MM Abu-Omar, PC Ford - RSC Sustainability, 2023 - pubs.rsc.org
Presented here is an overview of progress in one approach to reducing greenhouse gas
emission, namely substituting photosynthesis generated, woody biomass for fossil carbon as …

Transition metals promoting Mg-Al mixed oxides for conversion of ethanol to butanol and other valuable products: Reaction pathways

J Mück, J Kocík, M Hájek, Z Tišler, K Frolich… - Applied Catalysis A …, 2021 - Elsevier
This paper is focused on the catalytic synthesis of butanol from ethanol in a microflow
reactor at a constant weight hour space velocity (4.5 h− 1) and different reaction …

Highly selective 1-butanol obtained from ethanol catalyzed by mixed metal oxides: Reaction optimization and catalyst structure behavior

MR Siqueira, OM Perrone, G Metzker… - Molecular …, 2019 - Elsevier
Synthesis and characterization of a copper mixed metal oxide obtained from hydrotalcite
precursor as well as catalytic runs for ethanol conversion to 1-butanol are described …

Boosting the C–C Coupling of Bioethanol to Higher Alcohols by Inhibiting Aqueous Phase Reforming Reaction

X Wu, X Cai, Y Pi, B Chen, X Li, Q Meng… - Industrial & …, 2023 - ACS Publications
A suitable catalyst with an exact match of the acidity/basicity, ingenious geometric structure,
and proper electronic environment is vital to the Guerbet reaction for the synthesis of C6+ …

Upgrading of aqueous bioethanol to higher alcohols over NiSn/MgAlO catalyst

X Wu, X Cai, Q Zhang, P Bi, Q Meng, Y Pi… - ACS Sustainable …, 2021 - ACS Publications
The calorific value and cetane number of C4+ long-chain higher alcohols are similar to
those of diesel, blending with which can significantly reduce pollutant emissions from diesel …

A Pinch of Salt Improves n-Butanol Selectivity in the Guerbet Condensation of Ethanol over Cu-Doped Mg/Al Oxides

JA Barrett, ZR Jones, C Stickelmaier… - ACS Sustainable …, 2018 - ACS Publications
Improvement of processes that utilize renewable feedstocks to produce chemicals ordinarily
derived from fossil carbon feedstocks is paramount to creating environmentally sustainable …