Trans-effects in octahedral transition metal complexes
BJ Coe, SJ Glenwright - Coordination Chemistry Reviews, 2000 - Elsevier
An extensive survey of the occurrences and origins of both structural trans-effects (STEs)
and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This …
and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This …
Rhenium (VII) oxo and imido complexes: synthesis, structures, and applications
CC Romão, FE Kühn, WA Herrmann - Chemical reviews, 1997 - ACS Publications
The first examples of organometallic derivatives of metal oxides appeared in a syncretic
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …
Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent
E Arceo, JA Ellman, RG Bergman - Journal of the American …, 2010 - ACS Publications
A new method for the catalytic didehydroxylation of vicinal diols is described. Employing a
readily available low-valent rhenium carbonyl complex and a simple alcohol as a reducing …
readily available low-valent rhenium carbonyl complex and a simple alcohol as a reducing …
A hydrolytically stable oxo-rhenium (V) antitumor agent for synergistic combination therapy with cisplatin: from synthesis and mechanistic studies to toxicity …
SP Vaidya, M Manikandan, S Chhatar, S Dey… - Inorganic Chemistry …, 2023 - pubs.rsc.org
High-valent oxo-rhenium (V)(oxo-Re (V)) complexes are emerging as potential alternatives
to platinum (Pt)-based chemotherapeutics. While potent in vitro antitumor activity, novel …
to platinum (Pt)-based chemotherapeutics. While potent in vitro antitumor activity, novel …
A Simple Preparative Route to Bis(imido)uranium(VI) Complexes by the Direct Reductions of Diazenes and Azides
COMMUNICATIONS Page 1 COMMUNICATIONS Angew. Chem. Int. Ed. 1998, 37, No. 7
WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1998 1433-7851/98/3707-0959 $ 17.50+.50/0 …
WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1998 1433-7851/98/3707-0959 $ 17.50+.50/0 …
90Mo NMR and kinetic studies of peroxomolybdic intermediates involved in the catalytic disproportionation of hydrogen peroxide by molybdate ions
V Nardello, J Marko, G Vermeersch… - Inorganic Chemistry, 1995 - ACS Publications
In 1963, Khan and Kasha discovered that the reaction between hypochlorite ions and
hydrogen peroxide produces molecular oxygen in an excited singlet state (2,* 1 Ag). 1 …
hydrogen peroxide produces molecular oxygen in an excited singlet state (2,* 1 Ag). 1 …
A new generation of π-basic dearomatization agents
JM Keane, WD Harman - Organometallics, 2005 - ACS Publications
A new generation of dearomatizing π-bases having the general form {TpM (L)(π-
acid)}(where Tp= hydridotris (pyrazolyl) borate, M= rhenium, molybdenum, tungsten, L …
acid)}(where Tp= hydridotris (pyrazolyl) borate, M= rhenium, molybdenum, tungsten, L …
Comparison of the relative electron-donating abilities of hydridotris (pyrazolyl) borate and cyclopentadienyl ligands: Different interactions with different transition …
DM Tellers, SJ Skoog, RG Bergman, TB Gunnoe… - …, 2000 - ACS Publications
A comparison of the electron-donating abilities of the hydridotris (pyrazolyl) borate ligand
and cyclopentadienyl ligand toward transition metals is presented. These data demonstrate …
and cyclopentadienyl ligand toward transition metals is presented. These data demonstrate …
Kinetics and mechanisms of catalytic oxygen atom transfer with oxorhenium (V) oxazoline complexes
J Arias, CR Newlands, MM Abu-Omar - Inorganic Chemistry, 2001 - ACS Publications
The rhenium (V) monooxo complexes (hoz) 2Re (O) Cl (1) and [(hoz) 2Re (O)(OH2)][OTf](2)
have been synthesized and fully characterized (hoz= 2-(2 '-hydroxyphenyl)-2-oxazoline). A …
have been synthesized and fully characterized (hoz= 2-(2 '-hydroxyphenyl)-2-oxazoline). A …
C−N Bond Formation on Addition of Aryl Carbanions to the Electrophilic Nitrido Ligand in TpOs(N)Cl2
TJ Crevier, BK Bennett, JD Soper… - Journal of the …, 2001 - ACS Publications
The osmium (VI) nitrido complex TpOs (N) Cl2 (1) has been prepared from K [Os (N) O3] and
KTp in aqueous ethanolic HCl. It reacts rapidly with PhMgCl and related reagents with …
KTp in aqueous ethanolic HCl. It reacts rapidly with PhMgCl and related reagents with …