[HTML][HTML] Transition metal-free thiophene construction in pure water by multiplied CH functionalization with enaminones and elemental sulfur

L Tian, JP Wan, Y Liu - Green Synthesis and Catalysis, 2024 - Elsevier
A novel method for the synthesis of 2, 4-disubstituted thiophenes via the reactions of N, N-
disubstituted enaminones and elemental sulfur is developed. By simply heating the …

Iodine-catalyzed three-component annulation: access to highly fluorescent trisubstituted thiophenes

DB Rajkumar, K Gnanaoli, A Puhazhendhi… - Chemical …, 2023 - pubs.rsc.org
An efficient synthesis of highly fluorescent trisubstituted thiophenes was achieved via iodine-
catalyzed, base-promoted annulation employing elemental sulfur as a sulfur source. The …

Three-Component Reaction between 3-Acetylcoumarins, Amines, and Elemental Sulfur: A Designed Approach to 3-Amino-4H-thieno[3,2-c]coumarins

B Farajpour, R Heydarzadeh… - The Journal of …, 2024 - ACS Publications
In this work, a series of novel 3-amino-4 H-thieno [3, 2-c] coumarins were designed and
synthesized by a one-pot, catalyst-free, and three-component reaction of 3-acetylcoumarins …

One‐Pot Access to Tetrasubstituted 2‐Aminothiophenes via Regio‐and Chemoselective Domino Reactions of Dithioesters with Fumaronitrile at Room Temperature

AK Yadav, V Kumar, P Pali, S Ray… - Advanced Synthesis …, 2023 - Wiley Online Library
Herein, we report a one‐pot viable protocol to synthesize tetrasubstituted 2‐
aminothiophenes engaging readily accessible α‐enolic dithioesters and abundant …

LiBr-Promoted Reaction of β-Ketodithioesters and Thioamides with Sulfoxonium Ylides to Synthesize Functionalized Thiophenes

S Ray, N Gupta, MS Singh - Organic Letters, 2024 - ACS Publications
An operationally simple and highly efficient synthesis of functionalized thiophenes has been
developed by LiBr promoted heteroannulation of β-ketodithioesters and thioamides with …

Sulfur-and DABCO-Promoted Reaction between Alkylidene Rhodanines and Isothiocyanates: Access to Aminoalkylidene Rhodanines

B Farajpour, GB Alizadeh, S Majedi, F Moradkhani… - ACS …, 2024 - ACS Publications
In this work, an efficient sulfur-and DABCO-promoted reaction for the synthesis of
aminoalkylidene rhodanines from available alkylidene rhodanines and isothiocyanates is …

5.1. 7 Thiophene oligomers

AS SAr, AS SAr - Progress in Heterocyclic Chemistry, 2023 - books.google.com
There continues to be great interest from materials chemistry in thiophene oligomers with
two, three, or more thiophene units, for example, for use in small-molecule optoelectronic …

DABCO Mediated Sulfur Activation‐Intramolecular De‐Nitration Strategy for the Synthesis of Novel Dihydrothiochromeno[4,3‐c]pyrazoles

Deepika, AK Paul, CC Malakar… - Asian Journal of …, 2023 - Wiley Online Library
A facile and highly efficient metal‐free approach has been unfolded for the synthesis of
novel dihydrothiochromeno [4, 3‐c] pyrazoles using elemental sulfur as a powerful …

Five-membered ring systems: thiophenes and selenium/tellurium analogs and benzo analogs

JA Joule - Progress in Heterocyclic Chemistry, 2023 - Elsevier
The review covers work published in the calendar year 2022. References to new methods
for the ring synthesis of thiophenes, selenophenes, tellurophenes, and benzo analogs are …