Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes

R Maity, B Sarkar - JACS au, 2021 - ACS Publications
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Cooperative effects in multimetallic complexes applied in catalysis

R Maity, BS Birenheide, F Breher, B Sarkar - ChemCatChem, 2021 - Wiley Online Library
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

1H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes

G Guisado-Barrios, M Soleilhavoup… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Classical carbenes are usually described as neutral compounds featuring a
divalent carbon with only six electrons in their valence shell. It was only in 1988 that our …

High-performance photoelectrochemical water splitting of BiVO4@ Co-MIm prepared by a facile in-situ deposition method

S Zhou, P Yue, J Huang, L Wang, H She… - Chemical Engineering …, 2019 - Elsevier
Imidazole based cobalt (Co) complex (Co-MIm), constructed by the coordination between a
heteroaromatic ligand and a transmission metal that cherishes a low overpotential, strong …

Transition metal complexes of click-derived 1, 2, 3-triazoles as catalysts in various transformations: An overview and recent developments

MC Joseph, AJ Swarts, SF Mapolie - Coordination Chemistry Reviews, 2023 - Elsevier
The study of transition metal complexes linked with 1, 2, 3-triazoles has gained significant
attention due to their potential as effective catalysts in various chemical reactions. The 1, 2, 3 …

(Hetero) arylazo-1, 2, 3-triazoles:“Clicked” photoswitches for versatile functionalization and electronic decoupling

D Fang, ZY Zhang, Z Shangguan, Y He… - Journal of the …, 2021 - ACS Publications
The development of light-responsive chemical systems often relies on the rational design
and suitable incorporation of molecular photoswitches such as azobenzenes. Linking a …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

N-Heterocyclic carbene iron complexes catalyze the ring-opening polymerization of lactide

PVS Nylund, B Monney, C Weder… - Catalysis science & …, 2022 - pubs.rsc.org
Poly (lactic acid), PLA, which holds great promise as a biodegradable substitute of fossil
resource-derived polyolefins, is industrially produced by the ring-opening polymerization of …

Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction

L Suntrup, F Stein, J Klein, A Wilting… - Inorganic …, 2020 - ACS Publications
Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …