Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters

MJL Tschan, RM Gauvin, CM Thomas - Chemical Society Reviews, 2021 - pubs.rsc.org
This review highlights recent developments in the field of biodegradable polymeric materials
intended to replace non-degradable conventional plastics, focusing on studies from the last …

FI Catalysts for olefin polymerization A comprehensive treatment

H Makio, H Terao, A Iwashita, T Fujita - Chemical reviews, 2011 - ACS Publications
1.1. General Overview Polyolefinic materials, exemplified by polyethylenes (PEs),
polypropylenes (PPs), and ethylene/R-olefin amorphous copolymers, display many notable …

Coordination polymerization of polar vinyl monomers by single-site metal catalysts

EYX Chen - Chemical reviews, 2009 - ACS Publications
1.1 Background A prolific coupling of polymer science with organometallic chemistry has
recently yielded phenomenal scientific and commercial successes in the production of …

Secondary alkene insertion and precision chain-walking: A new route to semicrystalline “polyethylene” from α-olefins by combining two rare catalytic events

T Vaidya, K Klimovica, AM LaPointe… - Journal of the …, 2014 - ACS Publications
While traditional polymerization of linear α-olefins (LAOs) typically provides amorphous, low
T g polymers, chain-straightening polymerization represents a route to semicrystalline …

Salen-type aluminum and zinc complexes as two-faced Janus compounds: contribution to molecular sensing and polymerization catalysis

M Strianese, D Pappalardo, M Mazzeo… - Dalton …, 2020 - pubs.rsc.org
The aim of the present review is to highlight the most recent achievements in different fields
of application of salen-based zinc and aluminum complexes. More specifically this article …

Crystalline Isotactic Polar Polypropylene from the Palladium‐Catalyzed Copolymerization of Propylene and Polar Monomers

Y Ota, S Ito, M Kobayashi, S Kitade… - Angewandte …, 2016 - Wiley Online Library
Moderately isospecific homopolymerization of propylene and the copolymerization of
propylene and polar monomers have been achieved with palladium complexes bearing a …

Ni (II) α-diimine-catalyzed α-olefins polymerization: thermoplastic elastomers of block copolymers

G Leone, M Mauri, F Bertini, M Canetti, D Piovani… - …, 2015 - ACS Publications
The polymerization of ethylene with late transition metal complexes typically provides highly
branched amourphous poly (ethylene) s through a chain-walking mechanism, while the …

Microenvironment Modulation of Metal–Organic Frameworks (MOFs) for Coordination Olefin Oligomerization and (co) Polymerization

CL Zhang, T Zhou, YQ Li, X Lu, YB Guan, YC Cao… - Small, 2023 - Wiley Online Library
The majority of commercial polyolefins are produced by coordination polymerization using
early or late transition metal catalysts. Molecular catalysts containing these transition metals …

Palladium-catalyzed homo-and copolymerization of polar monomers: Synthesis of aliphatic and aromatic polymers

S Ito - Bulletin of the Chemical Society of Japan, 2018 - academic.oup.com
Transition-metal-catalyzed coordination–insertion polymerization of olefins is an
indispensable tool in polymer synthesis. When polar monomers with polar functional groups …

Electrochemical synthesis and properties of organonickel σ-complexes

DG Yakhvarov, AF Khusnuriyalova… - Organometallics, 2014 - ACS Publications
The organonickel complexes are organometallic compounds containing a Ni–C σ-bond (σ-
complexes). These species are very reactive and have been mainly characterized as the …