Small‐scale big science: From nano‐to atomically dispersed catalytic materials

L Wang, H Liu, J Zhuang, D Wang - Small Science, 2022 - Wiley Online Library
The emergence of nanomaterials (NMs) has made everyone more aware of the close
relationship between the size and performance of materials. Especially, the catalytic …

Toward efficient single-atom catalysts for renewable fuels and chemicals production from biomass and CO2

Y Lu, Z Zhang, H Wang, Y Wang - Applied Catalysis B: Environmental, 2021 - Elsevier
Transformation of biomass and CO 2 into renewable value-added chemicals and fuels has
been identified as a promising strategy to fulfill high energy demands, lower greenhouse …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

Increasing oxide reducibility: the role of metal/oxide interfaces in the formation of oxygen vacancies

A Ruiz Puigdollers, P Schlexer, S Tosoni… - Acs …, 2017 - ACS Publications
Reducibility is an essential characteristic of oxide catalysts in oxidation reactions following
the Mars–van Krevelen mechanism. A typical descriptor of the reducibility of an oxide is the …

O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Supported dual-atom catalysts: Preparation, characterization, and potential applications

J Zhang, Q Huang, J Wang, J Wang, J Zhang… - Chinese Journal of …, 2020 - Elsevier
Developing sustainable and clean electrochemical energy conversion technologies is a
crucial step in addressing the challenges of energy shortage and environmental pollution …

Titanium dioxide as a catalyst support in heterogeneous catalysis

S Bagheri, N Muhd Julkapli… - The scientific world …, 2014 - Wiley Online Library
The lack of stability is a challenge for most heterogeneous catalysts. During operations, the
agglomeration of particles may block the active sites of the catalyst, which is believed to …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J Xie - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Influence of Atomic-Level Morphology on Catalysis: The Case of Sphere and Rod-Like Gold Nanoclusters for CO2 Electroreduction

S Zhao, N Austin, M Li, Y Song, SD House… - ACS …, 2018 - ACS Publications
Gold-based materials hold promise in electrocatalytic reduction of CO2 to fuels. However,
the polydispersity of conventional gold nanostructures limits mechanistic studies. Here, we …

A Theoretical Study of Single-Atom Catalysis of CO Oxidation Using Au Embedded 2D h-BN Monolayer: A CO-Promoted O2 Activation

K Mao, L Li, W Zhang, Y Pei, XC Zeng, X Wu, J Yang - Scientific reports, 2014 - nature.com
The CO oxidation behaviors on single Au atom embedded in two-dimensional h-BN
monolayer are investigated on the basis of first-principles calculations, quantum Born …