Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

Comprehensive Summary Recently, piezocatalysis has attracted considerable attention as a
new type of renewable mechanical energy conversion technology, which relies on the strain …

Polymer materials suffer mechano-oxidative deterioration or degradation in the presence of
molecular oxygen and mechanical forces. In contrast, aerobic biological activities combined …

The combination of a nickel (II) catalyst and a mechanoredox catalyst under ball-milling
conditions promotes mechanical-force-driven C–N cross-coupling reactions. In this nickel …

Traditional mechanochemically controlled reversible‐deactivation radical polymerization
(RDRP) utilizes ultrasound or ball milling to regenerate activators, which induce side …

The sustainable synthesis of macromolecules with control over sequence and molar mass
remains a challenge in polymer chemistry. By coupling mechanochemistry and electron …

In recent years, redox reactions have harnessed light or mechanical energy to enable the
formation of chemical bonds. We postulated a complementary approach that …

Piezocatalysis offers a means to transduce mechanical energy into chemical potential,
harnessing physical force to drive redox reactions. Working in the solid state, we show here …

The development of mechanochemical tools for regulating the polymerization process has
received an increasing amount of attention in recent years. Herein, we report the example of …

Resonant acoustic mixing (RAM) enables mechanoredox catalysis with BaTiO3 as the
piezoelectric catalyst on model diazonium coupling reactions. RAM proceeds without formal …