Mixed perovskites (2D/3D)-based solar cells: a review on crystallization and surface modification for enhanced efficiency and stability

X Li, P Zhang, S Li, P Wasnik, J Ren, Q Jiang… - … Composites and Hybrid …, 2023 - Springer
Solar cells based on a three-dimensional (3D) crystalline perovskite framework exhibit
desired photoconversion efficiency. However, 3D perovskites are prone to surface defects …

Homomeric chains of intermolecular bonds scaffold octahedral germanium perovskites

A Morteza Najarian, F Dinic, H Chen, R Sabatini… - Nature, 2023 - nature.com
Perovskites with low ionic radii metal centres (for example, Ge perovskites) experience both
geometrical constraints and a gain in electronic energy through distortion; for these reasons …

Bright circularly polarized photoluminescence in chiral layered hybrid lead-halide perovskites

S Liu, M Kepenekian, S Bodnar, S Feldmann… - Science …, 2023 - science.org
Hybrid perovskite semiconductor materials are predicted to lock chirality into place and
encode asymmetry into their electronic states, while softness of their crystal lattice …

Leveraging Hierarchical Chirality in Perovskite (‐Inspired) Halides for Transformative Device Applications

T Duan, Y Zhou - Advanced Energy Materials, 2023 - Wiley Online Library
Chirality is an attribute based on the structural geometry of materials, which confers a
distinctive energy band structure for intriguing optical, electronic, and spintronic properties …

Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite

J Son, S Ma, YK Jung, J Tan, G Jang, H Lee… - Nature …, 2023 - nature.com
In principle, the induced chirality of hybrid perovskites results from symmetry-breaking within
inorganic frameworks. However, the detailed mechanism behind the chirality transfer …

Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals

G Chen, X Liu, J An, S Wang, X Zhao, Z Gu, C Yuan… - Nature Chemistry, 2023 - nature.com
Although their zero-to two-dimensional counterparts are well known, three-dimensional
chiral hybrid organic–inorganic perovskite single crystals have remained difficult because …

Elucidating the origin of chiroptical activity in chiral 2D perovskites through nano-confined growth

S Ma, YK Jung, J Ahn, J Kyhm, J Tan, H Lee… - Nature …, 2022 - nature.com
Chiral perovskites are being extensively studied as a promising candidate for spintronic-and
polarization-based optoelectronic devices due to their interesting spin-polarization …

Alkyl–aryl cation mixing in chiral 2D perovskites

L Yan, MK Jana, PC Sercel, DB Mitzi… - Journal of the American …, 2021 - ACS Publications
We report 2D hybrid perovskites comprising a blend of chiral arylammonium and achiral
alkylammonium spacer cations (1: 1 mole ratio). These new perovskites feature an …

The structural origin of chiroptical properties in perovskite nanocrystals with chiral organic ligands

YH Kim, R Song, J Hao, Y Zhai, L Yan… - Advanced Functional …, 2022 - Wiley Online Library
The authors investigate how chiral ligands attached to perovskite nanocrystal (PNC)
surfaces structurally distort the perovskite lattice. Chiral electro‐optical properties of the …

Chiral Cation Doping for Modulating Structural Symmetry of 2D Perovskites

Y Xie, J Morgenstein, BG Bobay, R Song… - Journal of the …, 2023 - ACS Publications
Cation mixing in two-dimensional (2D) hybrid organic–inorganic perovskite (HOIP)
structures represents an important degree of freedom for modifying organic templating …