This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Diverse late transition metal catalysts convert terminal or internal alkynes into transient
allylmetal species that display electrophilic or nucleophilic properties. Whereas classical …

Mn (III)-mediated formal [3+ 3]-annulation has been developed using readily available vinyl
azides and cyclopropanols with a wide range of substituents. Vinyl azides were successfully …

A facile, highly stereo-and regioselective hydrometalation of alkynes generating
alkenylmetal complex is disclosed for the first time from a reaction of alkyne, carboxylic acid …

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The additions of various nucleophiles (XeH) to carbonecarbon (CeC) multiple bonds are of
prime importance in synthetic organic chemistry. These essentially simple reactions allow …

Herein, we describe a regioselective Rh-catalyzed decarboxylative cross-coupling of β-keto
acids and alkynes to access branched γ, δ-unsaturated ketones. Rh-hydride catalysis …

Regio‐and enantioselective additions of alcohols to either terminal allenes or internal
alkynes provides access to allylic ethers by using a RhI/diphenyl phosphate catalytic system …

The design and catalytic implementation of tandem reactions to selectively create nitrogen-
containing products under mild conditions has encountered numerous challenges in …

Enantiomerically pure methyl Norphos (A), tolyl Norphos (B), CF3 Norphos (C), methyl
Renorphos (D), and tolyl Renorphos (E) were synthesized and used as chiral bisphosphine …