To produce substances with required physico-chemical properties demands the recognition
of structural features of materials. It includes polymorphism and isostructurality which are …

We report on the first examples of isolated silanol–silanolate anions, obtained by utilizing
weakly coordinating phosphazenium counterions. The silanolate anions were synthesized …

The reaction of a saline phosphazenium hydroxide hydrate with siloxanes led to a novel
kind of silanol‐silanolate anions. The weakly coordinating behavior of the cation renders the …

Clathrate compounds traditionally were discovered by happy accident because of the
considerable difficulty in predicting and controlling weak intermolecular forces in crystal …

Wir berichten über die ersten Beispiele isolierter Silanol‐Silanolat‐Anionen unter
Verwendung schwach koordinierender Phosphazenium‐Gegenionen. Die Silanolat …

The inclusion of small molecules, such as amines, into hydrogen-bonded assemblies is an
important task for a selective enclathration of substance mixtures. Here we report on a …

We report the synthesis and structures of two base‐free alkoxide dysprosium (III) complexes
of formula [Dy (L1) 2 (μ‐η6: η1‐Ph) 2BPh2]⋅ CH2Cl2 (1) and [Dy (L2) 2 (μ‐η6: η1‐Ph) …

The selective synthesis of new types of alumosiloxanes can be achieved by the reaction of
the bicyclic compound Al 2 [(OPh 2 Si) 2 O] 3· 2 Et 2 O (3) with water in donor solvents like …

The dibromodiquinoline derivative 2 yields crystalline lattice inclusion compounds with a
wide range of guest molecules. The solvent-free crystal structure is also formed. In all these …

The host compound triphenylsilanol (TPS) has been employed in the separation of the
isomers of picolinium chlorides (2PIC+, 3PIC+ and 4PIC+). By analogy with the Dutch …