Reactions at very low temperatures: gas kinetics at a new frontier

IWM Smith - Angewandte Chemie International Edition, 2006 - Wiley Online Library
A new era in chemical kinetics was heralded 20 years ago by the results reported by
Bertrand Rowe, then at the Laboratoire d AØrothermique in Meudon.[1] Using an apparatus …

Laboratory astrochemistry: gas-phase processes

IWM Smith - Annual Review of Astronomy and Astrophysics, 2011 - annualreviews.org
A major aim of astrochemistry is to explain the nature and abundance of the molecules
observed in the interstellar medium (ISM). Three kinds of activity are involved:(a) the …

Inhomogeneous RF fields: A versatile tool for the study of processes with slow ions

D Gerlich - Advances in chemical physics, 1992 - books.google.com
Inhomogeneous RF fields: A versatile tool for the study of processes with slow ions Page 17
INHOMOGENEOUS RF FIELDS: A VERSATILE TOOL FOR THE STUDY OF PROCESSES …

Experimental investigation of radiative association processes as related to interstellar chemistry

D Gerlich, S Horning - Chemical Reviews, 1992 - ACS Publications
As was originally discussed by Herbst and Klem-perer, 1 the low density and low
temperatureof interstellar regions restricts the gas-phase chemistry to exothermic binary …

Ion-neutral collisions in a 22-pole trap at very low energies

D Gerlich - Physica Scripta, 1995 - iopscience.iop.org
This contribution concentrates on the use of an ion trapping technique which has been
developed for studying collision processes and chemical reactions at low temperatures and …

Ultralow temperature kinetics of neutral–neutral reactions. The technique and results for the reactions CN+O2 down to 13 K and CN+NH3 down to 25 K

IR Sims, JL Queffelec, A Defrance… - The Journal of …, 1994 - pubs.aip.org
An entirely new experimental method is described which enables the rate constants of
neutral–neutral gas‐phase reactions to be measured at ultralow temperatures. The …

Experimental studies of gas-phase reactivity in relation to complex organic molecules in star-forming regions

IR Cooke, IR Sims - ACS Earth and Space Chemistry, 2019 - ACS Publications
The field of astrochemistry concerns the formation and abundance of molecules in the
interstellar medium, star-forming regions, exoplanets, and solar system bodies. These …

Reaction kinetics at very low temperatures: laboratory studies and interstellar chemistry

IWM Smith, BR Rowe - Accounts of Chemical Research, 2000 - ACS Publications
Studies of gas-phase processes at temperatures down to 10 K have recently blossomed,
largely through application of the CRESU (cinétique de réaction en ecoulement …

CRESU studies of ion/molecule reactions

BR Rowe, JB Marquette - International journal of mass spectrometry and …, 1987 - Elsevier
The CRESU (Cinétique de Réactions en Ecoulement Supersonique Uniforme) technique
allows ion/molecule reaction rate coefficients to be determined in the temperature range 8 …

Gas-phase ion dynamics and chemistry

PB Armentrout, T Baer - The Journal of Physical Chemistry, 1996 - ACS Publications
While the physical chemistry of gas-phase ions has its roots in traditional mass spectrometry,
the growth of the field during the past two decades can be attributed to the development and …