TADF: Enabling luminescent copper (i) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

Recent Advances in Solid‐State Lighting Devices Using Transition Metal Complexes Exhibiting Thermally Activated Delayed Fluorescent Emission Mechanism

GU Mahoro, J Fernandez‐Cestau… - Advanced Optical …, 2020 - Wiley Online Library
This review focuses on the state‐of‐the‐art of solid‐state lighting devices (SSLDs)—that is,
organic light‐emitting diodes (OLEDs) and light‐emitting electrochemical cells (LECs) …

Design of highly efficient deep-blue organic afterglow through guest sensitization and matrices rigidification

S Xu, W Wang, H Li, J Zhang, R Chen, S Wang… - Nature …, 2020 - nature.com
Blue/deep-blue emission is crucial for organic optoelectronics but remains a formidable
challenge in organic afterglow due to the difficulties in populating and stabilizing the high …

Hexaphenylbenzene‐based deep blue‐emissive metallacages as donors for light‐harvesting systems

H Liu, Z Zhang, C Mu, L Ma, H Yuan… - Angewandte Chemie …, 2022 - Wiley Online Library
We herein report the preparation of a series of hexaphenylbenzene (HPB)‐based deep blue‐
emissive metallacages via multicomponent coordination‐driven self‐assembly. These …

Aromatic Amides: A Smart Backbone toward Isolated Ultralong Bright Blue‐Phosphorescence in Confined Polymeric Films

K Zhang, LY Peng, XX Liu, X Xu, WH Fang… - Angewandte …, 2023 - Wiley Online Library
We describe an aromatic amide skeleton for manipulation of triplet excited states toward
bright long‐lived blue phosphorescence. Spectroscopic studies and theoretical calculations …

Long-lived room temperature phosphorescence of organic–inorganic hybrid systems

HR Wang, XG Yang, JH Qin, LF Ma - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Molecule-based crystalline materials with long-lived room temperature phosphorescence
have been paid tremendous attention due to their promising properties for the critical …

Status report on copper (I) complexes in photoredox catalysis; photophysical and electrochemical properties and future prospects

C Sandoval-Pauker, G Molina-Aguirre, B Pinter - Polyhedron, 2021 - Elsevier
Visible-light photoredox catalysis has become a practical tool in the last years for driving
energy-demanding chemical reactions. Owing to their exceptional photoelectrochemical …

Thermally activated delayed fluorescence in luminescent cationic copper (i) complexes

C Sandoval-Pauker, M Santander-Nelli, P Dreyse - RSC advances, 2022 - pubs.rsc.org
In this work, the photophysical characteristics of [Cu (N^ N) 2]+ and [Cu (N^ N)(P^ P)]+
complexes were described. The concept of thermally activated delayed fluorescence (TADF) …

Metal‐Induced Planar Chirality of Soft‐Bridged Binuclear Platinum (II) Complexes: 100% Phosphorescence Quantum Yields, Chiral Self‐Sorting, and Circularly …

J Song, H Xiao, B Zhang, L Qu, X Zhou… - Angewandte …, 2023 - Wiley Online Library
PtII complexes have attracted a great deal of interest due to their rich phosphorescent
properties. However, these square‐planar PtII complexes are far more likely to encounter …

Internal conversion rate constant calculations considering Duschinsky, anharmonic and Herzberg–Teller effects

RR Valiev, BS Merzlikin, RT Nasibullin… - Physical Chemistry …, 2023 - pubs.rsc.org
A novel method for calculating rate constants for internal conversion (kIC) that
simultaneously accounts for Duschinsky, anharmonic and Herzberg–Teller effects has been …