New chemistry of transition metal oxyhydrides

Y Kobayashi, O Hernandez, C Tassel… - … and Technology of …, 2017 - Taylor & Francis
In this review we describe recent advances in transition metal oxyhydride chemistry
obtained by topochemical routes, such as low temperature reduction with metal hydrides, or …

Property engineering in perovskites via modification of anion chemistry

Y Kobayashi, Y Tsujimoto… - Annual Review of …, 2018 - annualreviews.org
Perovskite-type oxides have proven to be a versatile class of compounds with systematic
study of their structure and various properties. Further structural variations and properties …

Two-dimensional Na–Cl crystals of unconventional stoichiometries on graphene surface from dilute solution at ambient conditions

G Shi, L Chen, Y Yang, D Li, Z Qian, S Liang, L Yan… - Nature Chemistry, 2018 - nature.com
NaCl in a 1: 1 stoichiometry is the only known stable form of the Na–Cl crystal under ambient
conditions, and non-1: 1 Na–Cl species can only form under extreme conditions, such as …

Chemical pressure-induced anion order–disorder transition in LnHO enabled by hydride size flexibility

H Yamashita, T Broux, Y Kobayashi… - Journal of the …, 2018 - ACS Publications
While cation order–disorder transitions have been achieved in a wide range of materials
and provide crucial effects in various physical and chemical properties, anion analogues are …

Synthesis and H− conductivity of a new oxyhydride Ba 2 YHO 3 with anion-ordered rock-salt layers

H Nawaz, F Takeiri, A Kuwabara… - Chemical …, 2020 - pubs.rsc.org
A new layered perovskite oxyhydride Ba2YHO3 was synthesized via high pressure
synthesis. Powder X-ray and neutron diffraction experiments revealed that in Ba2YHO3 the …

Ba2ScHO3: H Conductive Layered Oxyhydride with H Site Selectivity

F Takeiri, A Watanabe, A Kuwabara, H Nawaz… - Inorganic …, 2019 - ACS Publications
Hydride (H–) conduction is a new frontier related to hydrogen transport in solids. Here, a
new H–conductive oxyhydride Ba2ScHO3 was successfully synthesized using a high …

The role of π-blocking hydride ligands in a pressure-induced insulator-to-metal phase transition in SrVO2H

T Yamamoto, D Zeng, T Kawakami… - Nature …, 2017 - nature.com
Transition-metal oxyhydrides are of considerable current interest due to the unique features
of the hydride anion, most notably the absence of valence p orbitals. This feature …

Selective Synthesis of Perovskite Oxyhydrides Using a High-Pressure Flux Method

J Suzuki, H Okochi, N Matsui, T Nagase… - Journal of the …, 2023 - ACS Publications
Oxyhydrides with multi-anions (O2–and H–) are a recently developed material family and
have attracted attention as catalysts and hydride ion conductors. High-pressure and high …

Na3H(ZnH4) Antiperovskite: A Large Octahedral Distortion with an Off-Centering Hydride Anion Coupled to Molecular Hydride

S Gao, C Tassel, S Fujii, H Ubukata, T Zhu… - Chemistry of …, 2022 - ACS Publications
Inclusion of molecular ions with additional characteristics, including anisotropic shape,
magnetic moments, and bonding, widens the possibilities for controling and tuning the …

An empirical model for magnetic field dependent resistivity and magnetoresistance in manganites: application on polycrystalline charge-ordered La 0.4 Gd 0.1 Ca 0.5 …

A Krichene, W Boujelben, S Mukherjee… - Physical Chemistry …, 2018 - pubs.rsc.org
In this paper, we have investigated the electrical and magnetic response of a La0. 4Gd0.
1Ca0. 5MnO3 polycrystalline sample. This sample seems to exhibit fascinating phenomena …