Covalent organic frameworks enable sustainable solar to hydrogen peroxide

D Tan, R Zhuang, R Chen, M Ban… - Advanced Functional …, 2024 - Wiley Online Library
As a chemical product with rapidly expanding demand in the field of modern energy and
environmental applications, hydrogen peroxide (H2O2) has garnered widespread attention …

The photocatalytic H2O2 production by metal-free photocatalysts under visible-light irradiation

X Xu, Y Sui, W Chen, W Huang, X Li, Y Li, D Liu… - Applied Catalysis B …, 2023 - Elsevier
The photocatalytic H 2 O 2 production from H 2 O and O 2 over organic polymers is a
promising approach to achieve solar-to-chemical energy conversion. The continuous efforts …

Thiophene‐Containing Covalent Organic Frameworks for Overall Photocatalytic H2O2 Synthesis in Water and Seawater

JY Yue, LP Song, YF Fan, ZX Pan… - Angewandte Chemie …, 2023 - Wiley Online Library
H2O2 is a significant chemical widely utilized in the environmental and industrial fields, with
growing global demand. Without sacrificial agents, simultaneous photocatalyzed H2O2 …

Efficient photocatalytic production of hydrogen peroxide using dispersible and photoactive porous polymers

S Wang, Z Xie, D Zhu, S Fu, Y Wu, H Yu, C Lu… - Nature …, 2023 - nature.com
Developing efficient artificial photocatalysts for the biomimetic photocatalytic production of
molecular materials, including medicines and clean energy carriers, remains a …

Linkage microenvironment of azoles‐related covalent organic frameworks precisely regulates photocatalytic generation of hydrogen peroxide

Y Mou, X Wu, C Qin, J Chen, Y Zhao… - Angewandte Chemie …, 2023 - Wiley Online Library
Artificial H2O2 photosynthesis by covalent organic frameworks (COFs) photocatalysts is
promising for wastewater treatment. The effect of linkage chemistry of COFs as functional …

Site engineering of covalent organic frameworks for regulating peroxymonosulfate activation to generate singlet oxygen with 100% selectivity

Z Weng, Y Lin, S Guo, X Zhang, Q Guo… - Angewandte …, 2023 - Wiley Online Library
Abstract Singlet oxygen (1O2) is an excellent reactive oxygen species (ROSs) for the
selective conversion of organic matter, especially in advanced oxidation processes (AOPs) …

Regulating Relative Nitrogen Locations of Diazine Functionalized Covalent Organic Frameworks for Overall H2O2 Photosynthesis

Q Liao, Q Sun, H Xu, Y Wang, Y Xu, Z Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Nitrogen‐heterocycle‐based covalent organic frameworks (COFs) are considered promising
candidates for the overall photosynthesis of hydrogen peroxide (H2O2). However, the effects …

An Unlocked Two‐Dimensional Conductive Zn‐MOF on Polymeric Carbon Nitride for Photocatalytic H2O2 Production

Y Li, Y Guo, D Luan, X Gu, XW Lou - Angewandte Chemie, 2023 - Wiley Online Library
Developing highly efficient catalytic sites for O2 reduction to H2O2, while ensuring the fast
injection of energetic electrons into these sites, is crucial for artificial H2O2 photosynthesis …

Linkage-engineered donor–acceptor covalent organic frameworks for optimal photosynthesis of hydrogen peroxide from water and air

R Liu, Y Chen, H Yu, M Položij, Y Guo, TC Sum… - Nature Catalysis, 2024 - nature.com
Charge transfer and mass transport to catalytic sites are critical factors in photocatalysis.
However, achieving both simultaneously is challenging due to inherent trade-offs and …

Molecular‐Level Regulation Strategies Toward Efficient Charge Separation in Donor− Acceptor Type Conjugated Polymers for Boosted Energy‐Related …

L Wang, L Liu, Y Li, Y Xu, W Nie… - Advanced Energy …, 2024 - Wiley Online Library
The development of efficient photocatalysts for artificial photocatalytic energy conversion is
an intriguing strategy. Promisingly, conjugated polymers (CPs) have been actively …