Vertex‐Shared Linear Superatomic Molecules: Stepping Stones to Novel Materials Composed of Noble Metal Clusters

Y Niihori, S Miyajima, A Ikeda, T Kosaka… - Small …, 2023 - Wiley Online Library
Extremely small metal clusters composed of noble metal atoms (M) have orbitals similar to
those of atoms and therefore can be thought of as artificial atoms or superatoms. If these …

Atomic-level separation of thiolate-protected metal clusters

Y Negishi, S Hashimoto, A Ebina, K Hamada… - Nanoscale, 2020 - pubs.rsc.org
Fine metal clusters have attracted much attention from the viewpoints of both basic and
applied science for many years because of their unique physical/chemical properties and …

Evidence for triplet-state-dominated luminescence in biicosahedral superatomic molecular Au 25 clusters

M Mitsui, Y Wada, R Kishii, D Arima, Y Niihori - Nanoscale, 2022 - pubs.rsc.org
In photoluminescence (PL) quenching and triplet fusion upconversion experiments with
fluorescent organic-molecule quenchers, it was revealed that a rod-shaped, phosphine-and …

On the Origin of Photoluminescence Enhancement in Biicosahedral AgxAu25−x Nanoclusters (x = 0–13) and Their Application to Triplet–Triplet Annihilation …

M Mitsui, D Arima, Y Kobayashi, E Lee… - Advanced Optical …, 2022 - Wiley Online Library
Numerous reports hitherto show that the photoluminescence (PL) properties of metal
nanoclusters (NCs) can be enhanced by alloying the metal cores. In particular …

Triplet–triplet annihilation-based photon upconversion using nanoparticles and nanoclusters

Y Niihori, T Kosaka, Y Negishi - Materials Horizons, 2024 - pubs.rsc.org
The phenomenon of photon upconversion (UC), generating high-energy photons from low-
energy photons, has attracted significant attention. In particular, triplet–triplet annihilation …

Field Effect and Photoconduction in Au25 Nanoclusters Films

M Galchenko, A Black, L Heymann… - Advanced …, 2019 - Wiley Online Library
Quantum‐confined Au nanoclusters exhibit molecule‐like properties, including atomic
precision and discrete energy levels. The electrical conductivity of Au nanocluster films can …

Metal nanocluster‐based devices: Challenges and opportunities: Nanoscience: Special Issue Dedicated to Professor Paul S. Weiss

L Chen, A Black, WJ Parak, C Klinke… - Aggregate, 2022 - Wiley Online Library
Atomically precise nanoclusters (NCs) with fascinating physicochemical characteristics
different from their nanoparticles (NPs) counterparts have gained increasing attention in …

Purification and separation of ultra-small metal nanoclusters

D Li, B Kumari, X Zhang, C Wang, X Mei… - Advances in colloid and …, 2020 - Elsevier
Metal nanoclusters (NCs) are ultra-small nanoparticles intermediate in size between small
molecule complexes and nanoparticles. NCs with tunable surface functionality feature …

Controlling the Chemistry of Nanoclusters: From Atomic Precision to Controlled Assembly

S Basu, A Paul, R Antoine - Nanomaterials, 2021 - mdpi.com
Metal nanoclusters have gained prominence in nanomaterials sciences, owing to their
atomic precision, structural regularity, and unique chemical composition. Additionally, the …

Kernels‐Different Au25Nanoclusters Enhanced Catalytic Performance via Modification of Ligand and Electronic Effects

M Qu, F Xue, JY Wei, MM Qiao, WQ Ren… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Ultrasmall atomically precise thiolate‐protected gold
nanoclusters with surface open sites are crucial for practical applications in catalysis …