New insights into the structural transition from UO 2+ x to U 3 O 7 by quantitative Raman spectroscopy

JM Elorrieta, A Milena-Pérez, JF Vigier… - Physical Chemistry …, 2022 - pubs.rsc.org
The study of uranium oxides at different conditions is of paramount importance in the nuclear
field, especially regarding characterization of the spent nuclear fuel behavior in dry storage …

Polyepitaxial grain matching to study the oxidation of uranium dioxide

J Wasik, J Sutcliffe, R Podor, J Lewis… - npj Materials …, 2024 - nature.com
Although the principal physical behaviour of a material is inherently connected to its
fundamental crystal structure, the behaviours observed in the real-world are often driven by …

Charge order, frustration relief, and spin-orbit coupling in

R Saniz, G Baldinozzi, I Arts, D Lamoen, G Leinders… - Physical Review …, 2023 - APS
Research efforts on the description of the low-temperature magnetic order and electronic
properties of U 3 O 8 have been inconclusive so far. Reinterpreting neutron scattering …

Ab initio study of the adsorption of O, O2, H2O and H2O2 on UO2 surfaces using DFT+ U and non-collinear magnetism

I Arts, R Saniz, G Baldinozzi, G Leinders… - Journal of Nuclear …, 2024 - Elsevier
In order to model correctly the corrosion of spent nuclear fuel under disposal conditions, it is
important to understand its behavior in the presence of oxidants. To advance in this …

Pressure-induced structural and electronic phase transitions of uranium trioxide

JJ Ma, CB Zhang, R Qiu, P Zhang, B Ao, BT Wang - Physical Review B, 2021 - APS
The crystal structures, phonon spectra, and electronic properties of uranium trioxide (UO 3)
under high pressure have been systematically explored using a particle swarm optimization …

Oxidation of Micro- and Nanograined UO2 Pellets by In Situ Synchrotron X-ray Diffraction

E De Bona, K Popa, O Walter, M Cologna… - Inorganic …, 2022 - ACS Publications
When in contact with oxidizing media, UO2 pellets used as nuclear fuel may transform into
U4O9, U3O7, and U3O8. The latter starts forming by stress-induced phase transformation …

[PDF][PDF] Application of multi-edge HERFD-XAS to assess the uranium valence electronic structure in potassium uranate (KUO3)

R Bes, G Leinders, K Kvashnina - Journal of Synchrotron Radiation, 2022 - journals.iucr.org
The uranium valence electronic structure in the prototypical undistorted perovskite KUO3 is
reported on the basis of a comprehensive experimental study using multi-edge HERFD-XAS …

Refinement of the uranium dispersion corrections from anomalous diffraction

G Leinders, OG Grendal, I Arts, R Bes… - Journal of Applied …, 2024 - journals.iucr.org
The evolution of the uranium chemical state in uranium compounds, principally in the
oxides, is of concern in the context of nuclear fuel degradation under storage and repository …

[HTML][HTML] The Raman fingerprint of U3O7

JM Elorrieta, A Milena-Pérez, JF Vigier… - Journal of Nuclear …, 2024 - Elsevier
In this work, stoichiometric U 3 O 7 (ie, UO 2.33) has been prepared, its stoichiometry and
structure confirmed by TGA and XRD, respectively, and its Raman fingerprint described for …

Charge-lattice coupling and the dynamic structure of the U–O distribution in UO2+x

J Lewis, R Springell, C Bell, R Nicholls… - Frontiers in Nuclear …, 2024 - frontiersin.org
The different structures and behaviors of UO2+ x observed in crystallographic and local
structure measurements were examined by extended X-ray absorption fine structure …