Although the principal physical behaviour of a material is inherently connected to its fundamental crystal structure, the behaviours observed in the real-world are often driven by …
Research efforts on the description of the low-temperature magnetic order and electronic properties of U 3 O 8 have been inconclusive so far. Reinterpreting neutron scattering …
In order to model correctly the corrosion of spent nuclear fuel under disposal conditions, it is important to understand its behavior in the presence of oxidants. To advance in this …
JJ Ma, CB Zhang, R Qiu, P Zhang, B Ao, BT Wang - Physical Review B, 2021 - APS
The crystal structures, phonon spectra, and electronic properties of uranium trioxide (UO 3) under high pressure have been systematically explored using a particle swarm optimization …
E De Bona, K Popa, O Walter, M Cologna… - Inorganic …, 2022 - ACS Publications
When in contact with oxidizing media, UO2 pellets used as nuclear fuel may transform into U4O9, U3O7, and U3O8. The latter starts forming by stress-induced phase transformation …
R Bes, G Leinders, K Kvashnina - Journal of Synchrotron Radiation, 2022 - journals.iucr.org
The uranium valence electronic structure in the prototypical undistorted perovskite KUO3 is reported on the basis of a comprehensive experimental study using multi-edge HERFD-XAS …
G Leinders, OG Grendal, I Arts, R Bes… - Journal of Applied …, 2024 - journals.iucr.org
The evolution of the uranium chemical state in uranium compounds, principally in the oxides, is of concern in the context of nuclear fuel degradation under storage and repository …
In this work, stoichiometric U 3 O 7 (ie, UO 2.33) has been prepared, its stoichiometry and structure confirmed by TGA and XRD, respectively, and its Raman fingerprint described for …
J Lewis, R Springell, C Bell, R Nicholls… - Frontiers in Nuclear …, 2024 - frontiersin.org
The different structures and behaviors of UO2+ x observed in crystallographic and local structure measurements were examined by extended X-ray absorption fine structure …