Taking into account the vast arrays of fluorinated motifs known, 11 this review will be limited
to the monofluorination of organic compounds, ie, synthetic methods allowing the …

Charged intermediates and reagents are ubiquitous in organic transformations. The
interaction of these ionic species with chiral neutral, anionic, or cationic small molecules has …

Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Owing to the mild generation methods, arynes have been widely used in synthetic chemistry.
However, achieving asymmetric organocatalytic reactions with arynes remains a formidable …

Steric bulk controls CO (2) absorption: N-substituted amino acid salts in poly (ethylene
glycol) reversibly absorb CO (2) in nearly 1: 1 stoichiometry. Carbamic acid is thought to be …

Phase-transfer catalysis (PTC) is one of the most powerful catalytic manifolds for asymmetric
synthesis. Chiral cationic or anionic PTC strategies have enabled a variety of …

Abstract Geladene Intermediate und Reagentien sind in organischen Transformationen
ubiquitär. Die Wechselwirkungen dieser ionischen Spezies mit chiralen neutralen …

Due to the tremendous interest in carbon–fluorine bond-forming reactions, research efforts
in this area have been dedicated to the development of facile processes to synthesize small …

A practical and efficient method for the synthesis of cyclic carbonates from epoxides and
CO2 under mild reaction conditions was achieved via the use of a potassium iodide (KI) …

The recent advances in nucleophilic fluorination, regulated through hydrogen bonding
interactions are summarized. Two main categories of fluorine nucleophiles are discussed …