Physicochemical nature of perfluoroalkyl compounds induced by fluorine

T Hasegawa - The Chemical Record, 2017 - Wiley Online Library
Perfluoroalkyl (Rf) compounds have unique characters represented by a significantly high
hydrophobic property, which often makes us consider that Rf groups should be interacted …

MAIRS: Innovation of molecular orientation analysis in a thin film

T Hasegawa, N Shioya - Bulletin of the Chemical Society of …, 2020 - academic.oup.com
Multiple-angle incidence resolution spectrometry (MAIRS), originally developed in our
group, is a unique spectroscopic technique for analyzing the structure of molecular …

[图书][B] Quantitative infrared spectroscopy for understanding of a condensed matter

T Hasegawa - 2017 - Springer
Infrared (IR) spectroscopy strongly attracted the attention of theoretical physicists from the
1930s until the 1970s, and most of the important fundamentals were comprehensively …

Progress on highly proton-conductive polymer thin films with organized structure and molecularly oriented structure

Y Nagao - Science and technology of advanced materials, 2020 - Taylor & Francis
Several current topics are introduced in this review, with particular attention to highly proton-
conductive polymer thin films with organized structure and molecularly oriented structure …

Conformational Change of Alkyl Chains at Phase Transitions in Thin Films of an Asymmetric Benzothienothiophene Derivative

N Shioya, M Yoshida, M Fujii, T Shimoaka… - The Journal of …, 2022 - ACS Publications
Among many promising organic semiconducting materials, 2-decyl-7-phenyl [1] benzothieno
[3, 2-b][1] benzothiophene (Ph-BTBT-C10) shows outstanding device performances for …

Regioregularity-dependent crystalline structures and thermal transitions in poly (3-dodecylthiophene) s

H Park, MJ Han, Y Kim, EJ Kim, HJ Kim… - Chemistry of …, 2021 - ACS Publications
The liquid crystalline (LC) characteristics of conjugated polymers (CPs) can result in their
self-assembly with long-range ordering, providing an effective route for the formation of an …

Optimal experimental condition of IR pMAIRS calibrated by using an optically isotropic thin film exhibiting the berreman effect

N Shioya, S Norimoto, N Izumi, M Hada… - Applied …, 2017 - journals.sagepub.com
Infrared (IR) p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) is a
useful spectroscopic tool for revealing the molecular anisotropic structure in a thin film …

Simultaneous analysis of molecular orientation and quantity change of constituents in a thin film using pMAIRS

N Shioya, R Fujiwara, K Tomita… - The Journal of …, 2020 - ACS Publications
Spectral analysis using chemometrics is extensively used for quantitative chemical analysis
in a mixture, but it works powerfully only when the peak intensity is solely proportional to the …

Controlling mechanism of molecular orientation of poly (3-alkylthiophene) in a thin film revealed by using pMAIRS

N Shioya, T Shimoaka, K Eda, T Hasegawa - Macromolecules, 2017 - ACS Publications
A face-on oriented thin film of poly (3-hexylthiophene)(P3HT) is suitable for an organic
semiconductor layer in a photovoltaic device, and thus analysis of the film structure in terms …

Accurate molecular orientation analysis using infrared p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) considering the refractive index of the …

N Shioya, T Shimoaka, R Murdey… - Applied …, 2017 - journals.sagepub.com
Infrared (IR) p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) is a
powerful tool for analyzing the molecular orientation in an organic thin film. In particular …