Novel chiral iron phosphate complexes were prepared as catalysts for asymmetric oxidative
coupling reactions. These catalysts were applied for the synthesis of enantio-enriched C 1 …

A multidentate ligand platform is introduced that enables the isolation of both homo-and
heterobimetallic complexes of divalent first-row transition metal ions such as Mn (II), Fe (II) …

The mononuclear hydroxomanganese (III) complex,[MnIII (OH)(dpaq)]+, which is supported
by the amide-containing N5 ligand dpaq (dpaq= 2-[bis (pyridin-2-ylmethyl)] amino-N …

Oxo-metal-halide moieties have often been implicated as C–H bond activating oxidants with
the terminal oxo-metal entity identified as the electrophilic oxidant. The electrophilic …

Metalloproteins with active sites containing di-Fe cores exhibit diverse chemical reactivity
that is linked to the precise transfer of protons and electrons which directly involve the di-Fe …

Metalloproteins with dinuclear cores are known to bind and activate dioxygen, with a
subclass of these proteins having active sites containing FeMn cofactors and activities …

Class Ic ribonucleotide reductases (RNRIc) and R2-like ligand-binding oxidases (R2lox) are
known to contain heterobimetallic MnIIFeII cofactors. How these enzymes assemble MnIIFeII …

Assembly of heterobimetallic complexes is synthetically challenging due to the propensity of
ditopic ligands to bind metals unselectively. Here, we employ a novel divergent approach for …

The addition of Sc (OTf) 3 and Al (OTf) 3 to the mononuclear MnIII-hydroxo complex [MnIII
(OH)(dpaq)]+(1) gives rise to new intermediates with spectroscopic properties and chemical …

The synthesis, X-ray molecular structure, physico-chemical characterization and dual
antioxidant activity (catalase and superoxide dismutase) of a new polymeric mixed valence …