Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

The merger of photoredox and cobalt catalysis

M Kojima, S Matsunaga - Trends in Chemistry, 2020 - cell.com
In the past decade, synthetic chemists have discovered the outstanding generality and
potential of visible-light-driven photoredox catalysis, which converts visible light into …

Advancement in photocatalytic acceptorless dehydrogenation reactions: Opportunity and challenges for sustainable catalysis

PK Verma - Coordination Chemistry Reviews, 2022 - Elsevier
Dehydrogenation reactions are the challenging and thermodynamically unfavorable.
Traditionally, high temperature and pressure conditions, excess of oxidants and sacrificial …

Visible-light photoredox catalysis in water

C Russo, F Brunelli, GC Tron… - The Journal of Organic …, 2022 - ACS Publications
The use of water in organic synthesis draws attention to its green chemistry features and its
unique ability to unveil unconventional reactivities. Herein, literature about the use of water …

Rh/TiO2-Photocatalyzed Acceptorless Dehydrogenation of N-Heterocycles upon Visible-Light Illumination

NO Balayeva, Z Mamiyev, R Dillert, N Zheng… - ACS …, 2020 - ACS Publications
TiO2 is an effective and extensively employed photocatalyst, but its practical use in visible-
light-mediated organic synthesis is mainly hindered by its wide band gap energy. Herein, we …

Catalytic oxidative dehydrogenation of N-heterocycles with nitrogen/phosphorus co-doped porous carbon materials

K Sun, H Shan, R Ma, P Wang, H Neumann, GP Lu… - Chemical …, 2022 - pubs.rsc.org
A metal-free oxidative dehydrogenation of N-heterocycles utilizing a nitrogen/phosphorus co-
doped porous carbon (NPCH) catalyst is reported. The optimal material is robust against …

Recent advances of catalysis in the hydrogenation and dehydrogenation of N-heterocycles for hydrogen storage

KC Tan, T He, YS Chua, P Chen - The Journal of Physical …, 2021 - ACS Publications
Lack of efficient hydrogen storage method is one of the technical bottlenecks for the
implementation of hydrogen energy. Liquid organic hydrogen carriers (LOHCs), especially N …

Metallaphotoredox catalysis for sp3 C–H functionalizations through single-electron transfer

J Zhang, M Rueping - Nature Catalysis, 2024 - nature.com
Metallaphotoredox catalysis merging photocatalysis and transition metal catalysis is now the
most efficient platform for sp 3 C–H functionalizations due to its very efficient activation and …

Recent advances in the synthesis of N-heteroarenes via catalytic dehydrogenation of N-heterocycles

A Bera, S Bera, D Banerjee - Chemical Communications, 2021 - pubs.rsc.org
Bio-active molecules having N-heteroarene core are widely used for numerous medicinal
applications and as lifesaving drugs. In this direction, dehydrogenation of partially saturated …

Dual photoredox and cobalt catalysis enabled transformations

K Ram Bajya, S Selvakumar - European Journal of Organic …, 2022 - Wiley Online Library
Dual photoredox and cobalt catalysis opens a new and exciting avenue for transition metal
catalyzed cross‐coupling reaction. The ability of this approach to access low valent cobalt …