MJ Jaroszewicz, AR Altenhof… - Journal of the …, 2021 - ACS Publications
Chemical exchange saturation transfer (CEST) enhances solution-state NMR signals of labile and otherwise invisible chemical sites, by indirectly detecting their signatures as a …
M Novakovic, Ē Kupče, A Oxenfarth… - Nature …, 2020 - nature.com
Multidimensional TOCSY and NOESY are central experiments in chemical and biophysical NMR. Limited efficiencies are an intrinsic downside of these methods, particularly when …
Static satellite-transitions (ST) NMR line shapes from half-integer quadrupolar nuclei could be very informative: they can deliver insight about local motions over a wide range of …
2D NOESY and TOCSY play central roles in contemporary NMR. We have recently discussed how solvent-driven exchanges can significantly enhance the sensitivity of such …
M Novakovic, SF Cousin, MJ Jaroszewicz… - Journal of Magnetic …, 2018 - Elsevier
Cross-relaxation and isotropic mixing phenomena leading to the Nuclear Overhauser Effect (NOE) and to the TOCSY experiment, lie at the center of structural determinations by NMR …
MJ Jaroszewicz, M Novakovic… - The Journal of chemical …, 2022 - pubs.aip.org
Chemical exchange saturation transfer (CEST) is widely used for enhancing the solution nuclear magnetic resonance (NMR) signatures of magnetically dilute spin pools, in …
Purpose Saturation transfer MRI has previously been used to probe molecular binding interactions with signal enhancement via the water signal. Here, we detail the relayed …
T Wolf, Y Goobes, L Frydman - ChemPhysChem, 2024 - Wiley Online Library
Solid‐state NMR of low‐γ nuclides is often characterized by low sensitivity and by significant spectral broadenings induced by the quadrupolar and the chemical‐shift anisotropy …
Chemical exchange saturation transfer (CEST) NMR is widely used for enhancing the sensitivity of low-abundance exchanging sites in general, and for the water-based detection …