Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

This minireview aims to cover the developments over the past two decades in the chemistry
of sulfonium salts. Specifically, insight is provided into the synthetic strategies available for …

The synthesis of a new family of 10‐I‐3 hypervalent iodine compounds is described in which
the CF3 functionality participates directly in the hypervalent bond. These materials are …

This report details the development of a spirobiindane-based chiral hypervalent iodine
reagent, especially focusing on its structural elucidation for effective asymmetric induction of …

Development of the methodology for the preparation of vinyl sulfones is of significant interest
to organic chemists. Recently, numerous useful methods have been developed, mainly …

Molecular structures of the most prominent chiral non‐racemic hypervalent iodine (III)
reagents to date have been elucidated for the first time. The formation of a chirally induced …

An efficient and reliable electrochemical generator of hypervalent iodine reagents has been
developed. In the anodic oxidation of iodoarenes to hypervalent iodine reagents under flow …

In 1994, we first determined the single-electron-transfer (SET) oxidation ability of
phenyliodine (III) bis (trifluoroacetate)(PIFA) toward phenyl ethers, affording the …

United we stand! Cooperative activation of the hypervalent-iodine reagent TIPS-EBX with a
gold catalyst and a Brønsted acid allowed the first direct ethynylation of thiophenes at room …

Chiral hypervalent iodine chemistry has been steadily increasing in importance in recent
years. This review catalogues enantioselective transformations triggered by chiral …